Stereoselective synthesis of new enantiopure building blocks for the preparation of steroids

被引：0
|
作者：
Tietze, LF [1 ]
Ramachandar, T [1 ]
Vock, C [1 ]
机构：
[1] Univ Gottingen, Inst Organ Chem, D-37077 Gottingen, Germany
来源：
SYNLETT | 2003年 / 01期
关键词：
epoxidation; indane; oxidation; palladium; steroids;
D O I：
暂无
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The enantiopure alpha,beta-unsaturated ketone 4 was synthesised from indanone 2 by a palladium-catalysed hydrogenolysis of allylic formate 10 followed by deprotection of TBS-ether 11 and oxidation with MnO2.
引用
收藏
页码：118 / 120
页数：3
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