Synthesis, characterization and reactions of novel cycloketones C6H2(CH2)4(CO)2 and C6(CH2)6(CO)3

被引:0
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作者
Ullah, SS [1 ]
Alam, FR [1 ]
Haque, MR [1 ]
机构
[1] Jahangirnagar Univ, Dept Chem, Dhaka 1342, Bangladesh
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中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Reactions of AlCl3 with 2,3,5,6-tetramethylenebicyclo[2.2.0]hexanediironhexacarbonyl 3 and 1,2,3,4,5,6-hexamethylenecyclohexanenonacarbonyltriiron 5 in refluxing THF yield cycloketones [C6H2(CH2)(4)(CO)(2)] 4 and [C-6(CH2)(6)(CO)(3)] 6 respectively. The novel cycloketones 4 and 6 alo ng with 2,4-dinitrophenylhydrazine derivative of the 4 have been characterized by IR, H-1 NMR and mass spectra.
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页码:539 / 541
页数:3
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