Effect of physical barrier and anion-exchange process of nitrate-intercalated ZnAl layered double hydroxide films grown on Al on corrosion protection

被引:19
|
作者
Cao, Yanhui [1 ,2 ,3 ]
Zheng, Dajiang [4 ]
Lin, Changjian [1 ,2 ]
机构
[1] Xiamen Univ, State Key Lab Phys Chem Solid Surfaces, Xiamen 361005, Fujian, Peoples R China
[2] Xiamen Univ, Coll Chem & Chem Engn, Xiamen 361005, Fujian, Peoples R China
[3] Luoyang Ship Mat Res Inst, State Key Lab Marine Corros & Protect, Xiamen 361101, Peoples R China
[4] Xiamen Univ, Coll Mat, Xiamen 361005, Fujian, Peoples R China
来源
基金
中国国家自然科学基金;
关键词
Aluminum; Layered double hydroxide; XRD; Physical barrier; Anion-exchange; Corrosion protection mechanism; MAGNESIUM ALLOY; CONTROLLED-RELEASE; ANODIC FILMS; CARBON-STEEL; RESISTANCE; CONVERSION; INHIBITOR; ALUMINUM; COATINGS; BEHAVIOR;
D O I
10.1016/j.surfcoat.2021.127436
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
ZnAl layered double hydroxide (ZnAl-LDH) film loaded with nitrates was prepared on the surface of pure Al plate by hydrothermal reaction. The anion-exchange process of ZnAl-LDH in corrosive NaCl solution was demonstrated by the X-ray Diffraction (XRD). The corrosion protection behavior of this fabricated film was monitored by performing electrochemical impedance spectroscopy (EIS) up to 39 d. It was revealed that the physical barrier effect of nitrate-intercalated ZnAl-LDH film played a significant role in its corrosion protection and the anionexchange had a limited influence on final corrosion protection.
引用
收藏
页数:10
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