Nitrogen doped biomass-derived porous carbon as anode materials of lithium ion batteries

被引:57
|
作者
Wan, Hongri [1 ]
Hu, Xiaofang [1 ]
机构
[1] South China Univ Technol, Sch Mech & Automot Engn, Guangzhou 510640, Guangdong, Peoples R China
关键词
Rechargeable battery; Porous carbon; Lithium ion batteries; Anode material; HIGH-PERFORMANCE ANODE; LI-ION; MESOPOROUS CARBON; HIGH-CAPACITY; ELECTRICAL-CONDUCTIVITY; SULFUR; SPHERES; AEROGELS; NANOSPHERES; NANOSHEETS;
D O I
10.1016/j.ssi.2019.115030
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
N-doped biomass-derived porous carbon (N/C) with a 3D framework and large specific surface area was obtained by carbonizing bagasse biomass waste with melamine as nitrogen source. The obtained N/C has macroporous structures, rich mesoporous and microporous structures. The multi-grade pore structure can not only increase the specific surface area, but also effectively provide multi-layer electron transmission channels. N-doping can greatly enhance the interaction between anchor sites and lithium ions, because it can alter local electron density, which is conducive to lithium-ion adsorption and anchoring. As anode of lithium ion batteries (LIBs), it exhibits excellent reversible specific capacity of 530 mAh g(-1) at 0.1 A g(-1) after 100 cycles. Furthermore, this study demonstrates the employment of natural waste material as a potential anode for LIBs, which will definitively make a strike in the energy storage field.
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收藏
页数:8
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