High-resolution 13C NMR studies of cellulose and cellulose oligomers in ionic liquid solutions

被引：301
|
作者：
Moulthrop, JS
Swatloski, RP
Moyna, G
Rogers, RD
机构：
[1] Univ Sci Philadelphia, Dept Chem & Biochem, Philadelphia, PA 19104 USA
[2] Univ Alabama, Ctr Green Mfg, Tuscaloosa, AL 35487 USA
[3] Univ Alabama, Dept Chem, Tuscaloosa, AL 35487 USA
来源：
CHEMICAL COMMUNICATIONS | 2005年 / 12期
关键词：
D O I：
10.1039/b417745b
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
High-resolution C-13 NMR studies of cellulose and cellulose oligomers dissolved in the ionic liquid (IL) 1-butyl-3-methylimidazolium chloride ([ C(4)mim] Cl) show that the beta-( 1-->4)-linked glucose oligomers are disordered in this medium and have a conformational behavior which parallels the one observed in water, and thus, reveal that the polymer is disordered in IL solution as well.
引用
收藏
页码：1557 / 1559
页数：3
相关论文
共 50 条
  • [1] HIGH-RESOLUTION 13C CP/MAS NMR SPECTRA OF SOLID CELLULOSE OLIGOMERS AND THE STRUCTURE OF CELLULOSE II.
    Dudley, R.L.
    Fyfe, C.A.
    Stephenson, P.J.
    Deslandes, Y.
    Hamer, G.K.
    Marchessault, R.H.
    1600, (105):
  • [2] High-resolution 13C NMR studies of amylose and cellulose oligomers in 1-butyl-3-methylimidazolium chloride solutions.
    Moulthrop, JS
    Swatloski, RP
    Rogers, RD
    Moyna, G
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2004, 228 : U228 - U228
  • [3] HIGH-RESOLUTION C-13 CP/MAS NMR-SPECTRA OF SOLID CELLULOSE OLIGOMERS AND THE STRUCTURE OF CELLULOSE-II
    DUDLEY, RL
    FYFE, CA
    STEPHENSON, PJ
    DESLANDES, Y
    HAMER, GK
    MARCHESSAULT, RH
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1983, 105 (08) : 2469 - 2472
  • [4] CHARACTERIZATION OF CELLULOSE AND CELLULOSE DERIVATIVES IN SOLUTION BY HIGH-RESOLUTION C-13-NMR SPECTROSCOPY
    NEHLS, I
    WAGENKNECHT, W
    PHILIPP, B
    STSCHERBINA, D
    PROGRESS IN POLYMER SCIENCE, 1994, 19 (01) : 29 - 78
  • [5] HIGH-RESOLUTION NMR STUDIES ON CELLULOSE DERIVATIVES
    FRIEBOLI.H
    KEILICH, G
    SIEFERT, E
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1970, 9 (07) : 533 - &
  • [6] INVESTIGATION OF ALKALIZATION OF CELLULOSE BY HIGH-RESOLUTION C-13 SOLID NMR
    SCHROTER, B
    KUNZE, J
    PHILIPP, B
    ACTA POLYMERICA, 1981, 32 (11) : 730 - 732
  • [7] HIGH-RESOLUTION C-13-NMR SPECTROSCOPY OF SODIUM CARBOXY METHYL CELLULOSE
    CHAUDHARI, SNK
    GOUNDEN, KC
    SRINIVASAN, G
    EKKUNDI, VS
    JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 1987, 25 (01) : 337 - 342
  • [8] Characterization of cellulose and cellulose ethers by means of 13C NMR spectroscopy
    Kunze, J.
    Ebert, A.
    Fink, H.P.
    1600, Editura Acad Romane, Bucharest, Romania (34): : 1 - 2
  • [9] Characterization of cellulose and cellulose ethers by means of 13C NMR spectroscopy
    Kunze, J
    Ebert, A
    Fink, HP
    CELLULOSE CHEMISTRY AND TECHNOLOGY, 2000, 34 (1-2): : 21 - 34
  • [10] HIGH-RESOLUTION C-13 NMR-SPECTRA OF PREHYDROLYSIS OF PINE CELLULOSE SULFATE
    LUNDIN, AG
    PEN, RZ
    FILATOVA, VT
    SHAPIRO, IL
    VYSOKOMOLEKULYARNYE SOEDINENIYA SERIYA B, 1986, 28 (11): : 807 - 809
12345