Bio-based removable pressure-sensitive adhesives derived from carboxyl-terminated polyricinoleate and epoxidized soybean oil

A novel kind of fully bio-based PSAs were obtained through the curing reaction between two components derived from the plant oils: carboxyl-terminated polyricinoleate (PRA) from the castor oil and epoxidized soybean oil (ESO). The gel content, glass transition temperature (T-g), rheological behavior, tensile strength, creep resistance and 180 degrees peel strength of the PSAs were feasibly tailored by adjusting the component ratio of ESO to PRA. At low cross-linking level, the PSAs behaved like a viscous liquid and did not possess enough cohesiveness to sustain the mechanical stress during peeling. The PSAs cross-linked at or near the optimal stoichiometric conditions displayed an adhesive (interfacial) failure between the substrate and the adhesive layer, which were associated with the lowest adhesion levels. The PSAs with the dosage amount of ESO ranging from 10 similar to 20 wt% were tacky and flexible, which exhibited 180 degrees peel strength ranging from 0.4 similar to 2.3 N/cm; and could be easily removed without any residues on the adherend. The process for the preparation of the fully bio-based PSAs was environmentally friendly without using any organic solvent or other toxic chemical, herein showing the great potential as sustainable materials. (C) 2020 Chinese Chemical Society and Institute of Materia Medica, Chinese Academy of Medical Sciences. Published by Elsevier B.V. All rights reserved.