2D Metallosupramolecular Arrays of Zinc-5,10,15,20-tetra(4-pyridyl)porphyrin via Self-complementary Coordination and Peripheral Linkage

被引：8

作者：

Seidel, Ruediger W. ^{[1
]}

Oppel, Iris M. ^{[1
]}

机构：

[1] Ruhr Univ Bochum, Inst Analyt Chem, D-44780 Bochum, Germany

来源：

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 2010年 / 636卷 / 3-4期

关键词：

Crystal engineering; N ligands; Porphyrinoids; Zinc; X-ray diffraction; AXIAL COORDINATION; POLYMERS; METALLOPORPHYRINS; ARCHITECTURES; CLATHRATE; COMPLEXES; CHEMISTRY; NETWORKS; MODES;

D O I：

10.1002/zaac.200900388

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A structural study on two isotypic infinite 2D metallosupramolecular arrays of Zinc-5,10,15,20-tetra(4-pyridyl)porphyrin (ZnTPyP) has been undertaken. [ZnX2(mu(3)-ZnTPyP)center dot 3TCE](n) (X = Cl, Br; TCE = 1,1,2,2-tetrachloroethane) form extended 2D grid structures driven by self-complementary axial coordination of the metalloporphyrin entities. They both crystallize in the monoclinic system, P2(1)/c, Z = 4, a = 19.1176(15), b = 12.931(1), c = 21.8124(18) angstrom, beta= 103.306(8)degrees, V = 5247.6(7) angstrom(3) for X = Cl and a = 19.1644(7), b = 12.9984(5), c = 21.9013(9) angstrom, beta = 103.141(4), V = 5312.9(4) angstrom(3) for X = Br.

引用

页码：446 / 448

页数：3

共 24 条

[1] Supramolecular isomerism of self-complementary zinc-5,10,15,20-tetra(4-pyridyl)porphyrin in the presence of dimethylformamide
Seidel, Ruediger W.
Goddard, Richard
Foecker, Kirsten
Oppel, Iris M.
CRYSTENGCOMM, 2010, 12 (02): : 387 - 394
[2] 1D and 2D solid-state metallosupramolecular arrays of freebase 5,10,15,20-tetra(4-pyridyl)porphyrin, peripherally linked by zinc and manganese ions
Seidel, Rudiger W.
Oppel, Iris M.
STRUCTURAL CHEMISTRY, 2009, 20 (01) : 121 - 128
[3] 1D and 2D solid-state metallosupramolecular arrays of freebase 5,10,15,20-tetra(4-pyridyl)porphyrin, peripherally linked by zinc and manganese ions
Rüdiger W. Seidel
Iris M. Oppel
Structural Chemistry, 2009, 20 : 121 - 128
[4] Synthesis of Cationic Derivatives of 5,10,15,20-Tetra(4-pyridyl)porphyrin
E. A. Efimova
N. L. Pechnikova
A. V. Lyubimtsev
V. V. Aleksandriiskii
T. A. Ageeva
Russian Journal of General Chemistry, 2023, 93 : 1574 - 1578
[5] Synthesis of Cationic Derivatives of 5,10,15,20-Tetra(4-pyridyl)porphyrin
Efimova, E. A.
Pechnikova, N. L.
Lyubimtsev, A. V.
Aleksandriiskii, V. V.
Ageeva, T. A.
RUSSIAN JOURNAL OF GENERAL CHEMISTRY, 2023, 93 (06) : 1574 - 1578
[6] Electrochemical synthesis and properties of polyporphyrin films based on 5,10,15,20-tetra(4-pyridyl)porphyrin
Tesakova, Mariya V.
Syrbu, Sergey A.
Parfenyuk, Vladimir I.
MENDELEEV COMMUNICATIONS, 2023, 33 (01) : 90 - 92
[7] 5,10,15,20-tetra(4-pyridyl)porphyrinato zinc coordination polymeric particles with different shapes and luminescent properties
Sun, Wei
Wang, Hailong
Qi, Dongdong
Wang, Liang
Wang, Kang
Kan, Jinglan
Li, Wenjun
Chen, Yanli
Jiang, Jianzhuang
CRYSTENGCOMM, 2012, 14 (22): : 7780 - 7786
[8] Coordination and Metalation Bifunctionality of Cu with 5,10,15,20-Tetra(4-pyridyl)porphyrin: Toward a Mixed-Valence Two-Dimensional Coordination Network
Li, Yang
Xiao, Jie
Shubina, Tatyana E.
Chen, Min
Shi, Ziliang
Schmid, Martin
Steinrueck, Hans-Peter
Gottfried, J. Michael
Lin, Nian
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2012, 134 (14) : 6401 - 6408
[9] Organometallic boxes built from 5,10,15,20-tetra(4-pyridyl)porphyrin panels and hydroxyquinonato-bridged diruthenium clips
Barry, Nicolas P. E.
Govindaswarny, Padavattan
Furrer, Julien
Suess-Fink, Georg
Therrien, Bruno
INORGANIC CHEMISTRY COMMUNICATIONS, 2008, 11 (10) : 1300 - 1303
[10] Self-assembled monolayers formed by 5,10,15,20-tetra(4-pyridyl)porphyrin and cobalt 5,10,15,20-tetra(4-pyridyl)-21H,23H-porphine on iodine-passivated Au(111) as observed using electrochemical scanning tunneling microscopy and cyclic voltammetry
Thorgaard, Scott N.
Buehlmann, Philippe
JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 2012, 664 : 94 - 99

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