Preparation and properties of rare-earth containing oxide fluoride glasses

被引：15
|
作者：
Yonezawa, Susumu
Nishibu, Shiori
Leblanc, Marc
Takashima, Masayuki
机构：
[1] Univ Fukui, Grad Sch Engn, Fukui 9108507, Japan
[2] Univ Maine, Lab Oxydes & Flurures, UMR CNRS 6010, Fac Sci & Tech, F-72085 Le Mans 09, France
来源：
JOURNAL OF FLUORINE CHEMISTRY | 2007年 / 128卷 / 04期
关键词：
oxide fluoride glass; preparation; rare earth; optical property; magnetic property;
D O I：
10.1016/j.jfluchem.2006.12.002
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The preparation of the rare earth containing oxide fluoride glasses LnF(3) (Ln; Y through Lu)-BaF2,-AlF3-GeO2 in which the nominal content of LnF(3) reached 60 mol% in maximum and their basic properties such as density, refractive index and glass transition temperature were investigated and summarized in detail. Especially, in order to discuss the local structure around the rare earth ion in the glass, the Judd-Ofelt analysis (discussion with Omega parameters) of the HoF3-BaF2-AlF3-GeO2 glasses was carried out. The unique fluorescent behavior and the magnetic properties of LnF(3)-BaF2-AlF3-GeO2 glasses (Ln = Tb and/or Sm) were also studied. (C) 2006 Elsevier B.V. All rights reserved.
引用
收藏
页码：438 / 447
页数：10
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