Tandem catalysis: A sustainable alternative for direct hydrogenation of CO2 to light olefins

被引：30

作者：

Gambo, Yahya ^{[1
]}

Adamu, Sagir ^{[1
,2
]}

Lucky, Rahima A. ^{[4
]}

Ba-Shammakh, Mohammed S. ^{[1
]}

Hossain, Mohammad M. ^{[1
,2
,3
]}

机构：

[1] King Fahd Univ Petr & Minerals, Dept Chem Engn, Dhahran, Saudi Arabia

[2] King Fahd Univ Petr & Minerals, Interdisciplinary Res Ctr Refining & Adv Chem IRC, Dhahran, Saudi Arabia

[3] King Fahd Univ Petr & Minerals, Interdisciplinary Res Ctr Hydrogen & Energy Storag, Dhahran, Saudi Arabia

[4] Western Univ, Chem Reactor Engn Ctr, London, ON, Canada

来源：

APPLIED CATALYSIS A-GENERAL | 2022年 / 641卷

关键词：

Tandem catalysis; CO2; hydrogenation; Olefins; Fe-based; Metal-organic framework; Deactivation; HIGHLY SELECTIVE CONVERSION; METAL-ORGANIC FRAMEWORK; CARBON-DIOXIDE; HYDROCARBON SYNTHESIS; PROPANE DEHYDROGENATION; HETEROGENEOUS CATALYSIS; COMPOSITE CATALYST; IRON CATALYST; DESIGN; OXIDE;

D O I：

10.1016/j.apcata.2022.118658

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The design and development of novel tandem catalysts to facilitate the production of value-added chemicals and fuels via heterogeneous routes holds great prospect in revolutionizing the chemical industry. Herein, we discuss the fundamentals of tandem catalysis and provided a comprehensive account of recent advances related to the design and tuning of tandem catalysts for direct CO2 hydrogenation to light olefins. Moreover, insights on catalyst deactivation in tandem CO2 hydrogenation has been provided. In addition, the prospects of core-shell configuration and its high flexibility in implementing efficient tandem catalyst design strategies has been discussed. Most importantly, the insights and perspectives provided therein are hoped to stimulate and guide in the future design of highly efficient tandem catalysts that could enable the commercialization of the process as a sustainable and environmentally benign alternative for olefin production.

引用

页数：23

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