A low-n Rydberg state with vibrationally excited core assigned in the ZEKE-PFI spectrum of CS2

被引：0

作者：

CossartMagos, C

机构：

[1] Lab. de Photophysique Molec., Bât. 213, Université de Paris-Sud, 91405, Orsay Cedex

来源：

PHILOSOPHICAL TRANSACTIONS OF THE ROYAL SOCIETY A-MATHEMATICAL PHYSICAL AND ENGINEERING SCIENCES | 1997年 / 355卷 / 1729期

关键词：

D O I：

10.1098/rsta.1997.0085

中图分类号：

O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];

学科分类号：

07 ; 0710 ; 09 ;

摘要：

Polyatomic molecules offer the possibility of studying the dependence of vibrational autoionization rate on the nature of the particular vibrational modes involved. For example, in NO2, as stressed by E.R. Grant, the symmetric stretching relaxes much faster than the bending motion. A particular feature observed in the ZEKE-PFI spectrum of CS2 can be quoted as another example of the difficulty of relaxing the bending vibration in the ionic core of a triatomic molecule.

引用

页码：1697 / 1699

页数：3

共 9 条

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