Secondary coordination sphere controlled reversible geometry reorganisations in copper(II) complexes

被引：17
|
作者：
Fielden, J [1 ]
Long, DL [1 ]
Cronin, L [1 ]
机构：
[1] Univ Glasgow, Dept Chem, Glasgow G12 8QQ, Lanark, Scotland
来源：
CHEMICAL COMMUNICATIONS | 2004年 / 19期
关键词：
D O I：
10.1039/b407229d
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Reversible geometry reorganisations are demonstrated by cis-3,5-diamino-trans-hydroxycyclohexane (cis, trans-DAHC) copper(II) fluoride complexes, with the concentration of water in the mother liquor controlling interconversion between blue crystals of 5-coordinate syn-[Cu(DAHC)(2)F](F) . 2CH(3)OH . H2O and red crystals of 4-coordinate anti-[Cu(DAHC)(2)]( F)(2) . 2H(2)O.
引用
收藏
页码：2156 / 2157
页数：2
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