MCM-48 as a support for sulfonic acid catalysts

被引：31
|
作者：
Bandyopadhyay, M. [2 ]
Shiju, N. R. [3 ]
Brown, D. R. [1 ]
机构：
[1] Univ Huddersfield, Dept Chem & Biol Sci, Huddersfield HD1 3DH, W Yorkshire, England
[2] JIS Coll Engn, Dept Chem, Kalyani 741235, W Bengal, India
[3] Univ Amsterdam, Vant Hoff Inst Mol Sci, NL-1018 WV Amsterdam, Netherlands
来源：
CATALYSIS COMMUNICATIONS | 2010年 / 11卷 / 07期
关键词：
Mesoporous material; MCM-48; Microcalorimetry; Sulfonic acid functionalisation; PERIODIC MESOPOROUS ORGANOSILICAS; SELECTIVE SYNTHESIS; SILICAS; SBA-15; ADSORPTION; MONOLAYERS;
D O I：
10.1016/j.catcom.2010.01.018
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The ordered mesoporous silica, MCM-48, has been functionalised with sulfonic acid. Its physico-chemical properties have been compared with those of sulfonated MCM-41 and SBA-15. A higher catalytic activity for the functionalised MCM-48 in the alkylation of toluene with benzyl alcohol suggests that MCM-48 behaves as a better sulfonic acid support than MCM-41 and SBA-15. Ammonia adsorption calorimetric data shows that acid site strengths on the three supports are similar so the higher activity of MCM-48 sulfonic acid is probably due to better accessibility of its acid sites in the three-dimensional pore structure. (C) 2010 Elsevier B.V. All rights reserved.
引用
收藏
页码：660 / 664
页数：5
相关论文
共 50 条
  • [1] Hydrodesulfurization of dibenzothiophene over PtMo/MCM-48 catalysts
    Souza, Marcelo J. B.
    Pedrosa, Anne M. Garrido
    Cecilia, Juan A.
    Gil-Mora, Antonio M.
    Rodriguez-Castellon, Enrique
    [J]. CATALYSIS COMMUNICATIONS, 2015, 69 : 217 - 222
  • [2] CuO-containing MCM-48 as catalysts for phenol hydroxylation
    Lou, LL
    Liu, SX
    [J]. CATALYSIS COMMUNICATIONS, 2005, 6 (12) : 762 - 765
  • [3] Incorporated and supported VOx/MCM-48 catalysts:: A comparative study
    Mathieu, M
    Baltes, M
    Van der Voort, P
    Vansant, EF
    [J]. ADSORPTION SCIENCE AND TECHNOLOGY, 2000, : 643 - 647
  • [4] Simplified description of MCM-48
    Anderson, MW
    [J]. ZEOLITES, 1997, 19 (04): : 220 - 227
  • [5] Photoluminescence sites on MCM-48
    Shen, JL
    Lee, YC
    Liu, YL
    Yu, CC
    Cheng, PW
    Cheng, CF
    [J]. MICROPOROUS AND MESOPOROUS MATERIALS, 2003, 64 (1-3) : 135 - 143
  • [6] Stabilized MCM-48/VOx catalysts:: synthesis, characterization and catalytic activity
    Van Der Voort, P
    Baltes, M
    Vansant, EF
    [J]. CATALYSIS TODAY, 2001, 68 (1-3) : 119 - 128
  • [7] Characterization of MCM-48 materials
    Schumacher, K
    Ravikovitch, PI
    Du Chesne, A
    Neimark, AV
    Unger, KK
    [J]. LANGMUIR, 2000, 16 (10) : 4648 - 4654
  • [8] Characterization and hydrocracking of gas oil on sulfided NiW/MCM-48 catalysts
    Alsobaai, A. M.
    Zakaria, R.
    Hameed, B. H.
    [J]. CHEMICAL ENGINEERING JOURNAL, 2007, 132 (1-3) : 173 - 181
  • [9] Influence of surface properties of MCM-48 on the formation of a nanocomposite structure based on MCM-48 and PVA
    He, J
    Yang, J
    Zhang, SC
    Evans, DG
    Duan, X
    [J]. NANOTECHNOLOGY IN MESOSTRUCTURED MATERIALS, 2003, 146 : 383 - 386
  • [10] Mesoporous MCM-48 membrane synthesized on a porous stainless steel support
    Nishiyama, N
    Koide, A
    Egashira, Y
    Ueyama, K
    [J]. CHEMICAL COMMUNICATIONS, 1998, (19) : 2147 - 2148
12345