Isotope effects in C-H bond activation reactions by transition metals

被引：425
|
作者：
Jones, WD [1 ]
机构：
[1] Univ Rochester, Dept Chem, Rochester, NY 14627 USA
来源：
ACCOUNTS OF CHEMICAL RESEARCH | 2003年 / 36卷 / 02期
关键词：
D O I：
10.1021/ar020148i
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The activation of alkane C-H bonds by oxidative addition and its reverse reaction, reductive elimination, are believed to occur via transient a-alkane complexes. This Account summarizes how isotope effects can be used to probe the nature of these intermediates and points out some pitfalls in interpreting kinetic data. Comparisons are made with arene C-H activation and other activation systems.
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页码：140 / 146
页数：7
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