Facile new approach to high sulfur-content materials and preparation of sulfur-lignin copolymers

被引：41
|
作者：
Karunarathna, Menisha S. [1 ]
Tennyson, Andrew G. [1 ,2 ]
Smith, Rhett C. [1 ]
机构：
[1] Clemson Univ, Dept Chem, Clemson, SC 29634 USA
[2] Clemson Univ, Dept Mat Sci & Engn, Clemson, SC 29634 USA
来源：
JOURNAL OF MATERIALS CHEMISTRY A | 2020年 / 8卷 / 02期
基金：
美国国家科学基金会;
关键词：
ELEMENTAL SULFUR; INVERSE VULCANIZATION; DEGRADATION; POLYMERS; REAGENT;
D O I：
10.1039/c9ta10742h
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
This report introduces a new approach to high sulfur-content materials. This route, RASP (radical-induced aryl halide/sulfur polymerization), expands the substrate scope beyond olefins required for the traditional inverse vulcanization route to such materials. RASP allows direct reaction of two unmodified industrial waste products to give lignin-sulfur composites.
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页码：548 / 553
页数：6
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