Direct formation of Mg-Al-layered double-hydroxide films on glass substrate by the sol-gel method with hot water treatment

被引:27
|
作者
Yamaguchi, Naoko [1 ]
Ando, Daisuke [1 ]
Tadanaga, Kiyoharu [1 ]
Tatsumisago, Masahiro [1 ]
机构
[1] Osaka Prefecture Univ, Grad Sch Engn, Dept Appl Chem, Osaka 5998531, Japan
关键词
D O I
10.1111/j.1551-2916.2007.01711.x
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Amorphous Al2O3-MgO thin films with an Mg/Al ratio of unity were prepared on glass substrates by the sol-gel method with a heat treatment at 300 degrees C for 30 min. By immersing the films in water containing sodium hydroxide (pH 10-13) at 100 degrees C, nano-crystals of Mg-Al-layered double hydroxide (LDH) with a hexagonal structure, which is called hydrotalcite and the most basic composition of LDH, were precipitated on the amorphous Al2O3-MgO films. The maximum amount of Mg-Al nanocrystals was obtained when the film was immersed in basic solution of pH 12.
引用
收藏
页码:1940 / 1942
页数:3
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