Preparation and crystal structure of the azavinylidene derivative Cp2Ti(CH=CH2)(N=CPh2) derived from the thermally generated titanaallene intermediate [Cp2Ti=C=CH2]

被引：0

作者：

Beckhaus, R ^{[1
]}

Wagner, M ^{[1
]}

Wang, R ^{[1
]}

机构：

[1] Rhein Westfal TH Aachen, Inst Anorgan Chem, D-52056 Aachen, Germany

来源：

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 1998年 / 624卷 / 02期

关键词：

titanium; vinylidene complexes; azavinylidene compounds; crystal structure;

D O I：

10.1002/(SICI)1521-3749(199802)624:2<277::AID-ZAAC277>3.0.CO;2-T

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The title complex 4 was synthesized by reaction of Benzophenonimin with the titanaallene fragment [Cp-2*Ti=C=CH2] (3). Complex 4 was characterized by H-1 and C-13 NMR spectra and by X-ray structure analysis, respectively.

引用

页码：277 / 280

页数：4

共 50 条

[1] Darstellung und Kristallstruktur des Azavinylidenderivates Cp*2Ti(CH=CH2)(N=CPh2) ausgehend vom thermisch gebildeten Titanaallenintermediat [Cp*2Ti=C=CH2]
Beckhaus, R.
Wagner, M.
Wang, R.
Zeitschrift fuer Anorganische und Allgemeine Chemie, 624 (02):
[2] Reactions of the titanaallene intermediate [Cp*2Ti=C=CH2] with isonitriles:: An approach to the chemistry of radialene type molecules
Santamaría, C
Beckhaus, R
Haase, D
Koch, R
Saak, W
Strauss, I
ORGANOMETALLICS, 2001, 20 (07) : 1354 - 1359
[3] Reactivity of acetylenes toward the titanocene vinylidene fragment [Cp*2Ti=C=CH2]. Formation of methylenetitanacyclobutenes and vinyltitanium acetylides. Crystal and molecular structures of Cp*2TiCR'=CR''C=CH2 (R'=R''=CH3; R'=SiMe(3), R''=C6H5) and Cp*2Ti(CH=CH2)(C CPh)
Beckhaus, R
Sang, J
Wagner, T
Ganter, B
ORGANOMETALLICS, 1996, 15 (04) : 1176 - 1187
[4] CONTRASTING THE CP(3)MCL/LI(CH2)(CH2)PPH(2) (M=U, TH) SYSTEMS - SYNTHESIS AND STRUCTURE OF CP(2)TH[(CH2)(CH2)PPH(2)](2)
CRAMER, RE
HITT, J
CHUNG, T
GILJE, JW
NEW JOURNAL OF CHEMISTRY, 1995, 19 (5-6) : 509 - 514
[5] Preparation and crystal structure of bis(pi-pentamethylcyclopentadienyl) (2-methylene)(3-diphenylmethylene)oxatitanacyclobutane Cp*Ti-2-OC(=CPh2)-C=CH2
Beckhaus, R
Strauss, I
Wagner, T
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1997, 623 (04): : 654 - 658
[6] PREPARATION OF METALLOCYCLES OF TITANIUM OF THE TYPES CP2TI(CH2)3NRC2H4RN(CH2)3TICP2 AND CP2TI(CH2)3NRR'
SCHREER, H
FROHLICH, HO
ZEITSCHRIFT FUR CHEMIE, 1983, 23 (09): : 347 - 348
[7] THE ORGANIC AND ORGANOMETALLIC CHEMISTRY OF CP2TI=CH2
GRUBBS, RH
STRAUS, DA
FINCH, W
OTT, KC
BUCHWALD, S
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1983, 185 (MAR): : 147 - INOR
[8] Synthesis of semibridging μ-vinylidene titanium-copper and -gold complexes.: Crystal and molecular structure of Cp*2Ti(Cl)(μ-C=CH2)AuPPh3
Beckhaus, R
Oster, J
Wang, RM
Bohme, U
ORGANOMETALLICS, 1998, 17 (11) : 2215 - 2221
[9] Trapping of Cp*W(NO)(eta(2)-PhC CH), the key intermediate in the C-H activation of alkanes by Cp*W(NO)(CH2SiMe3)(CPh=CH2)
Legzdins, P
Lumb, SA
ORGANOMETALLICS, 1997, 16 (09) : 1825 - 1827
[10] REACTIONS OF CP2TI=CH2 SOURCES WITH ACID ANHYDRIDES AND IMIDES
CANNIZZO, LF
GRUBBS, RH
JOURNAL OF ORGANIC CHEMISTRY, 1985, 50 (13): : 2316 - 2323

← 1 2 3 4 5 →

Preparation and crystal structure of the azavinylidene derivative Cp*2Ti(CH=CH2)(N=CPh2) derived from the thermally generated titanaallene intermediate [Cp*2Ti=C=CH2]

Preparation and crystal structure of the azavinylidene derivative Cp2Ti(CH=CH2)(N=CPh2) derived from the thermally generated titanaallene intermediate [Cp2Ti=C=CH2]