Modification of interface of water/AOT/isooctane reverse micelles by halogenated organodiselenides

被引：13
|
作者：
Mehta, S. K. [1 ]
Kaur, Khushwinder
Bhasin, K. K.
机构：
[1] Panjab Univ, Dept Chem, Chandigarh 160014, UT, India
来源：
COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS | 2010年 / 355卷 / 1-3期
关键词：
Microemulsions; Organodiselenides; Temperature and water induced percolation; Thermodynamics of droplet clustering; W/O MICROEMULSIONS; OIL MICROEMULSIONS; FT-IR; WATER; AOT; PERCOLATION; SURFACTANT; DYNAMICS; FLUORESCENCE; AGGREGATION;
D O I：
10.1016/j.colsurfa.2009.11.027
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The paper reports the modification of interface of water/AOT(sodium bis(2-ethylhexyl)sulfosuccinate)/isooctane reverse micelles by the influence of organodiselenides viz., C10H6N2F2Se2 and C10H6N2Cl2Se2 employing fluorescence and UV-vis absorption spectroscopy. The interfacial modification has been further confirmed by FTIR studies. The physico-chemical behavior of the system has been investigated employing conductivity, which clearly shows the phenomenon of percolation. The obtained results have been explained on the basis of scaling laws and activation energy of percolation. Results have also been evaluated to throw light on the thermodynamics of droplet clustering. (C) 2009 Elsevier B.V. All rights reserved.
引用
收藏
页码：37 / 44
页数：8
相关论文
共 50 条
  • [1] Water content in AOT/isooctane reverse micelles
    Qiu, Jun-Hong
    Dong, Shu-Jie
    Xie, Hai-Ying
    Gao Xiao Hua Xue Gong Cheng Xue Bao/Journal of Chemical Engineering of Chinese Universities, 2008, 22 (03): : 515 - 518
  • [2] Ultrafiltration of reverse micelles in the ternary system AOT/isooctane/water
    Schomacker, R
    Braun, GA
    LANGMUIR, 1996, 12 (10) : 2362 - 2366
  • [3] Water Dynamics at the Interface in AOT Reverse Micelles
    Moilanen, David E.
    Fenn, Emily E.
    Wong, Daryl
    Fayer, M. D.
    JOURNAL OF PHYSICAL CHEMISTRY B, 2009, 113 (25): : 8560 - 8568
  • [4] CHARACTERISTICS OF TYROSINASE IN AOT-ISOOCTANE REVERSE MICELLES
    BRU, R
    SANCHEZFERRER, A
    GARCIACARMONA, F
    BIOTECHNOLOGY AND BIOENGINEERING, 1989, 34 (03) : 304 - 308
  • [5] Determination of the Water/AOT/Isooctane Reverse Micelles Size Parameters from Their Refractive Index Data
    El Aferni, Ahmed
    Guettari, Moez
    Tajouri, Tahar
    JOURNAL OF SOLUTION CHEMISTRY, 2017, 46 (01) : 89 - 102
  • [6] Determination of the Water/AOT/Isooctane Reverse Micelles Size Parameters from Their Refractive Index Data
    Ahmed El Aferni
    Moez Guettari
    Tahar Tajouri
    Journal of Solution Chemistry, 2017, 46 : 89 - 102
  • [7] Effect of CO2 on the properties of AOT/water/isooctane reverse micelles by fluorescence study
    Liu, DX
    Zhang, JL
    Fan, JF
    Han, BX
    Chen, J
    JOURNAL OF PHYSICAL CHEMISTRY B, 2004, 108 (09): : 2851 - 2856
  • [8] Synthesis of stabilized zirconia ultrafine powders using AOT-isooctane-water reverse micelles
    Yang, CF
    Chen, JY
    JOURNAL OF MATERIALS SCIENCE LETTERS, 1997, 16 (11) : 936 - 938
  • [9] Molecular modeling and simulations of AOT-Water reverse micelles in isooctane: Structural and dynamic properties
    Abel, S
    Sterpone, F
    Bandyopadhyay, S
    Marchi, M
    JOURNAL OF PHYSICAL CHEMISTRY B, 2004, 108 (50): : 19458 - 19466
  • [10] Characterization of patatin esterase activity in AOT-isooctane reverse micelles
    Jiménez, M
    Escribano, J
    Gandía-Herrero, F
    Chazarra, S
    Cabanes, J
    García-Carmona, F
    Pérez-Gilabert, M
    BIOTECHNOLOGY PROGRESS, 2002, 18 (03) : 635 - 640
12345