A promising Ti/SnO2 anodes modified by Nb/Sb co-doping

被引:28
|
作者
Chen, Aging [1 ]
Xia, Shengjian [1 ]
Pan, Haiyue [1 ]
Xi, Junhua [1 ]
Qin, Haiying [1 ]
Lu, Hongwei [1 ]
Ji, Zhenguo [1 ]
机构
[1] Hangzhou Dianzi Univ, Coll Mat & Environm Engn, Hangzhou 310018, Zhejiang, Peoples R China
基金
中国国家自然科学基金;
关键词
Ti/Nb-Sb-SnO2; anodes; Dip coating; Electrochemical performance; SPRAY-PYROLYSIS; ELECTROCHEMICAL OXIDATION; ELECTRODES; OXIDE; PERFORMANCE; FILMS; DEGRADATION; NITROGEN; PHENOL;
D O I
10.1016/j.jelechem.2018.07.033
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
Electrochemical properties of Ti/SnO2 anodes, such as oxygen evolution potential, current efficiency and service lifetime, have been enhanced significantly by Nb/Sb co-doping. Characterization of X-ray diffraction (XRD) and X-ray photoelectron spectroscopy (XPS) indicated that Nb substituted Sn in SnO2 lattice with the chemical state of Nb5+. Electrochemical impedance spectroscopy (EIS) measurement showed that Ti/Nb-Sb-SnO2 anodes, compared to Ti/Nb-Sb-SnO2 anodes, have a lower charge transfer resistance, exhibiting more efficient electrocatalytic activity. These results suggest that Ti/Nb-Sb-SnO2 anodes are suitable for use in wastewater treatment.
引用
收藏
页码:169 / 174
页数:6
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