SYNTHESIS AND SPECTRAL INVESTIGATIONS OF COVALENTLY LINKED PHTHALOCYANINE-C60 DYAD VIA FLEXIBLE CARBON LINKER

被引:4
|
作者
Sukeguchi, Daisuke [1 ]
Yoshiyama, Hideyuki [1 ]
Singh, Surya Prakash [1 ]
Shibata, Norio [1 ]
Nakamura, Shuichi [1 ]
Toru, Takeshi [1 ]
Hayashi, Yasuhiko [1 ]
Soga, Tetsuo [1 ]
机构
[1] Nagoya Inst Technol, Grad Sch Engn, Dept Frontier Mat, Showa Ku, Nagoya, Aichi 4668555, Japan
关键词
phthalocyanine; fullerene; hybrid molecule; flexible carbon linker; electronic communication; ORGANIC SOLAR-CELLS; CONJUGATED POLYMER; FULLERENE; ELECTROCHEMISTRY; PHOTOVOLTAICS;
D O I
10.1515/HC.2009.15.4.263
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Phthalocyanine-C-60 dyad 1 via a flexible saturated carbon linker was synthesized. The UV/Vis and fluorescence spectra studies of I revealed that intramolecular, not intermolecular, photoinduced electronic communication was observed in the solution state. We also examined UV-Vis and fluorescence spectra of a mixture of C-60 and conventional tetra tert-Bu phthalocyanine 2 for comparison
引用
收藏
页码:263 / 272
页数:10
相关论文
共 31 条
  • [1] Protonation-Induced Changes in the Photophysical Properties of a Phthalocyanine and a Covalently-Linked, Phthalocyanine-C60 Fullerene Dyad
    Bottari, Giovanni
    Kahnt, Axel
    Guldi, Dirk M.
    Torres, Tomas
    ECS JOURNAL OF SOLID STATE SCIENCE AND TECHNOLOGY, 2013, 2 (10) : M3145 - M3150
  • [2] Synthesis and Spectral Properties of Phthalocyanine-Methylpheophorbide a Covalently Linked Dyad
    Balashova, Irina O.
    Pushkarev, Victor E.
    Shestov, Vladimir I.
    Tomilova, Larisa G.
    Koifman, Oscar I.
    Ponomarev, Gelii V.
    MACROHETEROCYCLES, 2015, 8 (03): : 233 - 238
  • [3] Synthesis and photophysical characterization of a titanium(IV) phthalocyanine-C60 supramolecular dyad
    Ballesteros, B
    de la Torre, G
    Torres, T
    Hug, GL
    Rahman, GMA
    Guldi, DM
    TETRAHEDRON, 2006, 62 (09) : 2097 - 2101
  • [4] Highly conductive supramolecular nanostructures of a covalently linked phthalocyanine-C60 fullerene conjugate
    Bottari, Giovanni
    Olea, David
    Gomez-Navarro, Cristina
    Zamora, Felix
    Gomez-Herrero, Julio
    Torres, Tomas
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2008, 47 (11) : 2026 - 2031
  • [5] Ordering phthalocyanine-C60 fullerene conjugates on individual carbon nanotubes
    Bottari, Giovanni
    Olea, David
    Lopez, Vicente
    Gomez-Navarro, Cristina
    Zamora, Felix
    Gomez-Herrero, Julio
    Torres, Tomas
    CHEMICAL COMMUNICATIONS, 2010, 46 (26) : 4692 - 4694
  • [6] Synthesis and spectroscopic properties of a covalently linked porphyrin-fullerene C60 dyad
    Milanesio, M. Elisa
    Durantini, Edgardo N.
    SYNTHETIC COMMUNICATIONS, 2006, 36 (15) : 2135 - 2144
  • [7] Synthesis and photophysical studies of a new nonaggregated C60-silicon phthalocyanine-C60 triad
    Martin-Gomis, Luis
    Ohkubo, Kei
    Fernandez-Lazaro, Fernando
    Fukuzumi, Shunichi
    Sastre-Santos, Angela
    ORGANIC LETTERS, 2007, 9 (17) : 3441 - 3444
  • [8] Synthesis and characterization of a peptide-linked C60 dyad
    Bianco, A
    Maggini, M
    Mondini, S
    Polese, A
    Scorrano, G
    Toniolo, C
    Guldi, DM
    RECENT ADVANCES IN THE CHEMISTRY AND PHYSICS OF FULLERENES AND RELATED MATERIALS, VOL 6, 1998, 98 (08): : 1145 - 1151
  • [9] Photorefractive polymer composites using a trinitrofluorenone-C60 dyad with a conformationally flexible linker as photosensitizer
    Martin-Gomis, Luis
    Fernandez-Lazaro, Fernando
    Sastre-Santos, Angela
    Quintana, Jose A.
    Villalvilla, Jose M.
    Boj, Pedro
    Diaz-Garcia, Maria A.
    SYNTHETIC METALS, 2007, 157 (24) : 1064 - 1070
  • [10] Synthesis of mesogenic phthalocyanine-C60 donor-acceptor dyads designed for molecular heterojunction photovoltaic devices
    Geerts, Yves Henri
    Debever, Olivier
    Amato, Claire
    Sergeyev, Sergey
    BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY, 2009, 5