Recent advances in the boration and cyanation functionalization of alkenes and alkynes

被引:6
|
作者
Ahmad, Muhammad Siddique [1 ]
Meguellati, Kamel [1 ]
Wang, Qifeng [2 ]
机构
[1] Jinan Univ, Sch Pharm, 855 Xingye Ave East, Guangzhou 511436, Peoples R China
[2] Jilin Univ, Coll Chem, 2699 Qianjin St, Changchun 130012, Peoples R China
关键词
Metal catalyst; Boronation; Hydroboronation; Dehydroboronation; Cyanation; Hydrocyanation; Cyanomethylation; Alkynes; Alkenes; NICKEL-CATALYZED CARBOCYANATION; CROSS-COUPLING REACTION; ONE-POT SYNTHESIS; TERMINAL ALKYNES; TRANS-HYDROBORATION; INTERNAL ALKYNES; STEREOSELECTIVE HYDROBORATION; DEHYDROGENATIVE BORYLATION; PROMOTED HYDROBORATION; EFFICIENT SYNTHESIS;
D O I
10.1016/j.jscs.2022.101483
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Alkenyl boron-esters and acrylonitrile groups are key structural functional groups found in dyes, pesticides, fluorescent compounds, functional materials, and biologically active drugs. Considerable efforts have been devoted for the introduction of boron-esters and acrylonitrile groups by using alkenes and alkynes conversion routes for boronation, hydroboronation, dehydrogenative boronation, cyanation, hydrocyanation, alkylcyanation, cyanomethylation. These reported methodologies are very valuable for the industrial production of acrylonitriles and alkenyl boron esters.(c) 2022 The Author(s). Published by Elsevier B.V. on behalf of King Saud University. This is an open access article under the CC BY-NC-ND license (http://creativecommons.org/licenses/by-nc-nd/4.0/).
引用
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页数:22
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