FI automatic method for the determination of copper(II) based on coproporphyrin I-Cu(II)/TCPO/H2O2 chemiluminescence reaction for the screening of waters

In this paper, an automatic method for the screening of water samples containing Cu(II) was proposed, based on peryoxalate chemiluminescence reaction using coproporphyrin I as fluorophor compound to provide selectivity and a simple flow injection (H) chemiluminescence detector (CLD). FI system conditions were chosen in order to distinguish samples over or under legislation limit established (50 mug l(-1)) with high reliability. The detection limit found was 9 mug l(-1) and the linear dynamic range was 15-125 mug l(-1) of Cu(II). Repeatibility and reproducibility studies gave good precision and accuracy with recovery near 100%. Under these conditions, the method resulted selective and only Fe(II), Fe(Ill) and Pb(II) could interfere, but at a concentration level higher than their normal concentration in waters. The proposed method was found to be highly reliable for screening purposes and it was successfully applied to the screening of a variety of real water samples. (C) 2004 Elsevier B.V. All rights reserved.