Origin of the Xiaohekou skarn copper deposit and related granitoids in the Zha-Shan ore cluster area, South Qinling, China

The Xiaohekou copper deposit is one of the few typical skarn-type, commercial deposits in the Zha-Shan ore cluster area in the eastern part of South Qinling. The ore-related granitoids in the Xiaohekou mining district include a number of small plutons of granodiorite porphyry and granite porphyry, as well as numerous dykes. They are characterized by relatively low SiO2 (65.9-73.3 wt%) and MgO (0.26-1.72 wt%) contents, variable Mg# (29.4-64.0) values, high K2O (3.11-5.75 wt%) content and negligible delta Eu (1.00-1.15) values. The samples also exhibit depletion in Cr, Ni, Nb, Ta, and Ti content, and high Sr/Y (46.6-64.7) and La/Yb (17.0-25.0) ratios. These features are similar to those of high-K talc-alkaline adaldte-like magma formed by partial melting of thickened lower crust in continental collision zones or intracontinental settings. The majority of the samples have T-DM2(Hf) of 1.5-1.2 Ga, corresponding to weakly negative epsilon(Hf)(t) values ( - 4.75 to - 0.13) typical of crustal material, but more than one quarter have T-DMI(Hf) of 0.80-0.71 Ga, corresponding to positive epsilon(Hf)(t) values of + 0.07 to + 2.45, indicating that the granitoids resulted from partial melting of Mesoproterozoic lower crustal rocks with significant input from enriched lithospheric mantle-derived magmas. Zircons from the Xiaohekou granitoids have Delta FMQ values concentrated around -0.62 to +5.54, most of which show the magma fO(2) of FMQ to HM, in accordance with the widespread occurrence of magnetite, hematite and specularite in the Xiaohekou skarn system, which is an indicator of relatively high fO(2) for a magmatic-hydrothermal system. The granitoids exhibit similar or even higher Ce4+/Ce3+ (average of 452) and Eu/Eu* (average of 0.72) values in comparison with those of fertile Cu deposits worldwide, indicating that the Xiaohekou granitoids may possess the potential to form a large magmatic-hydrothermal Cu deposit. Zircons of the granitoids show obvious positive correlations between oxidation indices (Ce and Eu anomalies, Ce4+/Ce3+ ratios, and AFMQ values) and epsilon(Hf)(t) values, implying the involvement of an oxidized mantle component which might have caused the fO(2) elevation and played an important role in the formation of Cu deposits. The zircon U-Pb ages (141.3 +/- 1.3 and 138.1 +/- 2.0 Ma) of the Xiaohekou ore-related granitoids obtained in this study are similar to the zircon U-Pb and molybdenite Re-Os ages yielded from porphyry Mo mineralization at the Chigou and Lengshuigou deposits in the Zha-Shan ore district, indicating that they are possibly part of a single tectonic, magmatic, and metallogenic event in the Yanshan orogeny. The ore-related granitoids in the Xiaohekou area were formed in a post-collisional compression-extension transition regime during the Early Cretaceous Qinling intracontinental orogeny. The orogeny can be attributed to the far-field effect of a switch from pre-Mesozoic Tethyan tectonics to Late Mesozoic Pacific tectonics. This triggered a stress field transition from N-S to E-W trending and from intracontinental subduction thickening to large-scale lithospheric delamination and thinning.