Low Toxic Corrosion Inhibitors for Amine-based CO2 Capture Process

被引:24
|
作者
Srinivasan, Sureshkumar [1 ]
Veawab, Amornvadee [1 ]
Aroonwilas, Adisorn [1 ]
机构
[1] Univ Regina, Fac Engn & Appl Sci, Energy Technol Lab, Regina, SK S4S 0A2, Canada
来源
GHGT-11 | 2013年 / 37卷
关键词
Corrosion inhibitor; CO2; capture; amine; thiosulfate; electrochemical tests; weight loss tests;
D O I
10.1016/j.egypro.2013.05.182
中图分类号
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号
0807 ; 0820 ;
摘要
This work evaluated inhibition performance of a low toxic corrosion inhibitor, namely sodium thiosulfate, on carbon steel in 5.0 kmol/m(3) monoethanolamine (MEA) solution at 80 degrees C and 0.55 mol/mol CO2 loading. Effects of corrosion inhibitor concentration and process contaminants, including formate and chloride, on inhibition performance were studied. The results show that sodium thiosulfate significantly reduced corrosion rate with an inhibition efficiency of up to 94% in short term exposure tests, but did not perform well in long term exposure tests due to the instability of passive film. Its inhibition efficiency was not affected by the presence of chloride and formate. (C) 2013 The Authors. Published by Elsevier Ltd. Open access under CC BY-NC-ND license. Selection and/or peer-review under responsibility of GHGT
引用
收藏
页码:890 / 895
页数:6
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