Approaches to conjugated polymers via new solid state polymerizations

被引：7

作者：

Sandman, DJ ^{[1
]}

Njus, JM ^{[1
]}

Tran, B ^{[1
]}

机构：

[1] Univ Massachusetts, Dept Chem, Ctr Adv Mat, Lowell, MA 01854 USA

来源：

MACROMOLECULAR SYMPOSIA | 2004年 / 216卷

关键词：

conjugated polymers; monoacetylenes; nitriles; polydiacetylenes; solid state polymerization; thermal reactivity;

D O I：

10.1002/masy.200451209

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Solid state polymerization is the most convenient approach for the synthesis of macroscopic polymer single crystals. Motivations for seeking fully crystalline specimens of conjugated polymers other than polydiacetylenes (PDA) are presented. The thermal reactivity of p-ethynylbenzoiic acid (EBA) is found to be a topochemically initiated solid state polymerization. The studies of EBA led to a new paradigm for solid state reactivity in such systems. Systems related to the paradigm, namely p-cyanobenzoic acid (CNBA) and p-cyanocinnamic acid (CNCA) have been studied. Sublimation competed with thermal processes in CNBA and CNCA, and a detailed product description has proved difficult to date. Thermochromism and charge-transfer transitions in PDA are discussed.

引用

页码：77 / 85

页数：9

共 50 条

[1] Approaches to conjugated polymers via solid state polymerization
Sandman, DJ
Kim, RB
Nius, JM
Lee, DC
Cholli, SL
Sahoo, S
MACROMOLECULAR SYMPOSIA, 2003, 192 : 99 - 113
[2] Topochemical polymerizations for the solid-state synthesis of organic polymers
Hema, Kuntrapakam
Ravi, Arthi
Raju, Cijil
Pathan, Javed R.
Rai, Rishika
Sureshan, Kana M.
CHEMICAL SOCIETY REVIEWS, 2021, 50 (06) : 4062 - 4099
[3] New approaches to the synthesis of pure conjugated polymers
Svoboda, Jan
Blaha, Michal
Sedlacek, Jan
Vohlidal, Jiri
Balcar, Hynek
Mav-Golez, Ida
Zigon, Majda
ACTA CHIMICA SLOVENICA, 2006, 53 (04) : 407 - 416
[4] Computational approaches toward the nonlinear optical properties of conjugated organic polymers in the solid-state.
Kirtman, B
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1999, 218 : U499 - U499
[5] Controlled polymerizations for the synthesis of semiconducting conjugated polymers
Okamoto, Ken
Luscombe, Christine K.
POLYMER CHEMISTRY, 2011, 2 (11) : 2424 - 2434
[6] Conjugated polymers as solid-state laser materials
Hide, F
Schwartz, BJ
Diaz-Garcia, MA
Heeger, AJ
SYNTHETIC METALS, 1997, 91 (1-3) : 35 - 40
[7] Conjugated polymers by solid-state metathesis polycondensation
Delgado, Paula Andrea
Kean, Zachary
Wagener, Kenneth B.
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2011, 241
[8] The synthesis of fluorene/thiophen-based conjugated polymers via solid-state reaction
College of Chemistry and Chemical Engineering, Xinjiang University, Urumqi 830046, China
不详
Gongneng Cailiao, 2008, 8 (1242-1245): : 1242 - 1245
[9] Approaches to new conjugated polymers from dicyanoalkenes and -arenes
Sandman, DJ
Rixman, MA
Tsai, Z
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1999, 217 : U439 - U439
[10] Conjugated microporous polymers promote photoswitching in the solid-state
Liu, Tianbao
Ji, Yinghao
Wu, Qinyu
Sun, Fanxi
Zhu, Gaolu
Zheng, Yonghao
Wei, Chen
Wang, Dongsheng
JOURNAL OF MACROMOLECULAR SCIENCE PART A-PURE AND APPLIED CHEMISTRY, 2024, 61 (05): : 289 - 304

← 1 2 3 4 5 →