Fungal metabolites, 47.: Columbetdione, a new cyclopentene derivative from the fruiting bodies of Tricholoma columbetta (Basidiomycetes) -: Structure and synthesis
被引:8
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作者:
Vadalà, A
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机构:
Univ Pavia, Dipartimento Chim Organ, I-27100 Pavia, ItalyUniv Pavia, Dipartimento Chim Organ, I-27100 Pavia, Italy
Vadalà, A
[1
]
Finzi, PV
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机构:
Univ Pavia, Dipartimento Chim Organ, I-27100 Pavia, ItalyUniv Pavia, Dipartimento Chim Organ, I-27100 Pavia, Italy
Finzi, PV
[1
]
Zanoni, G
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Univ Pavia, Dipartimento Chim Organ, I-27100 Pavia, ItalyUniv Pavia, Dipartimento Chim Organ, I-27100 Pavia, Italy
Zanoni, G
[1
]
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机构:
Vidari, G
[1
]
机构:
[1] Univ Pavia, Dipartimento Chim Organ, I-27100 Pavia, Italy
ketones;
natural products;
structure elucidation;
total synthesis;
synthetic methods;
D O I:
10.1002/ejoc.200390104
中图分类号:
O62 [有机化学];
学科分类号:
070303 ;
081704 ;
摘要:
A chemical investigation of the fruiting bodies of Tricholoma columbetta (Agaricaceae, Basidiomycetes) led to the isolation of columbetdione, an unprecedented cyclopentene derivative. The structure was determined by spectroscopic methods and molecular modelling and unambiguously cone firmed by total synthesis. ((C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2003).