Synthesis, Characterization and Crystal Structure of Two Metal-Organic Complexes with MOPIP

被引：0

作者：

Huang Yan-Ju ^{[1
,2
]}

Ni Liang ^{[1
]}

Du Gang ^{[3
]}

Cui Yun-Cheng ^{[4
]}

Zhang Wen-Li ^{[1
]}

Wang Lei ^{[1
]}

Hao Xiang-Rong ^{[2
]}

机构：

[1] Jiangsu Univ, Sch Chem & Chem Engn, Zhenjiang 212013, Jiangsu, Peoples R China

[2] Tonghua Teachers Coll, Dept Chem, Tonghua 134002, Jilin, Peoples R China

[3] Tonghuas 1 Middle Sch, Tonghua 134001, Jilin, Peoples R China

[4] Jilin Normal Univ, Coll Chem, Siping 136000, Jilin, Peoples R China

来源：

CHINESE JOURNAL OF INORGANIC CHEMISTRY | 2010年 / 26卷 / 07期

关键词：

2-(4-methoxyphenyl)-1H-imidazo[4,5-f][1,10] phenanthroline; Manganese(II); Cadmium(II); HYDROTHERMAL SYNTHESIS; COORDINATION POLYMERS;

D O I：

暂无

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Two unusual zero-dimensional (OD) compounds, viz. [Cd(MOPIP)(3)(H2O)(9)](4n) (1) and [Mn(MOPIP)(3)(H2O)(6)](2n). (2), are synthesized by the combination of two different metallic salts and 2-(4-methoxypheny1)-1H-imidazo[4,5-f] [1,10] phenanthroline (MOPIP) ligand. The compounds have been hydrothermally synthesized and structurally characterized by elemental analysis, IR. spectrum, TG and single-crystal X-ray diffraction. The results show that every metal ion is hexa-coordinated with six nitrogen atoms from three different MOPIP ligands in the crystal structure, showing a slightly distorted octahedral geometry. CCDC: 775844, 1; 775845, 2.

引用

页码：1269 / 1273

页数：5

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