Effect of nucleating agents on the crystallization of Li2O-Al2O3-SiO2 system glass

被引:19
|
作者
Hu, AM [1 ]
Liang, KM [1 ]
Wang, G [1 ]
Zhou, F [1 ]
Peng, F [1 ]
机构
[1] Tsing Hua Univ, Dept Mat Sci & Engn, Beijing 100084, Peoples R China
关键词
crystallization; differential thermal analysis; glass-ceramics; nucleation;
D O I
10.1007/s10973-004-0465-9
中图分类号
O414.1 [热力学];
学科分类号
摘要
The processes of nucleation of Li2O-Al2O3-SiO2 glasses with TiO2 and TiO2+ZrO2 as nucleating agents were discussed. The DTA peak temperature and DTA peak height shown a strong dependence on the nucleation temperature in the glass with TiO2, while in the glass with TiO2+ZrO2, this tendency was small. The optimum nucleation temperatures were 745 and 760degreesC for two glasses. It suggested that with TiO2+ZrO2 as nucleating agents, the crystallization had lower sensitivity for nucleation temperature, and the glass had higher nucleation efficiency than with TiO2.
引用
收藏
页码:991 / 997
页数:7
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