Effect of composition on the Raman response of the Cu2(Fe x Zn1-x)SnS4 and Cu2(Mn x Zn1-x)SnS4 solid solutions

被引：1

作者：

Suss, Nicole ^{[1
,2
]}

Heppke, Eva M. ^{[2
]}

Avci, Fatma D. ^{[2
]}

Appelt, Oona ^{[1
]}

Efthimiopoulos, Ilias ^{[1
]}

机构：

[1] GFZ German Res Ctr Geosci, D-14473 Potsdam, Germany

[2] Tech Univ Berlin, Inst Chem, Str 17 Juni 135, D-10623 Berlin, Germany

来源：

ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES | 2022年 / 77卷 / 06期

关键词：

composition; kesterite; Raman spectroscopy; solid solution; stannite; CU2ZNSNS4; THIN-FILMS; KESTERITE CU2ZNSNS4; OPTICAL-PROPERTIES; SCATTERING; STANNITE; DISORDER; SPECTROSCOPY; DIFFRACTION; DEFECTS; CZTS;

D O I：

10.1515/znb-2022-0045

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

We have examined the effect of composition on the Raman-active vibrational response of the Cu-2(FexZn1-x)SnS4 and Cu-2(MnZn1-x)SnS4 solid solution series at ambient conditions. Based on these results we were able to identify the phase boundaries of the respective kesterite-type and stannite-type structures adopted by these compounds as a function of composition. In the case of Cu-2(FexZn1-x)SnS4, our observations correlate very well with earlier reports. For the Cu-2(Mn-x Zn1-x)SnS4 series, on the other hand, we were able to clearly pinpoint the kesterite <-> stannite transition for intermediate compositions for the first time, indicating that Raman spectroscopy can serve as an efficient method for monitoring subtle structural transitions in these systems.

引用

页码：425 / 432

页数：8

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