Thermo-Analytical and Physico-Chemical Characterization of Woody and Non-Woody Biomass from an Agro-ecological Zone in Nigeria

被引:0
|
作者
Balogun, Ayokunle O. [1 ,2 ]
Lasode, Olumuyiwa A. [2 ]
McDonald, Armando G. [1 ]
机构
[1] Univ Idaho, Dept Forest Rangeland & Fire Sci, Moscow, ID 83844 USA
[2] Univ Ilorin, Dept Mech Engn, Fac Engn & Technol, Ilorin, Nigeria
来源
BIORESOURCES | 2014年 / 9卷 / 03期
关键词
Ash; Biomass; Nigeria; TGA; Calorific value; GC/MS; FAST PYROLYSIS; PY-GC/MS; COMBUSTION; HEMICELLULOSE; COMPONENTS; CELLULOSE; BEHAVIOR; KINETICS; LIGNIN; STRAW;
D O I
暂无
中图分类号
TB3 [工程材料学]; TS [轻工业、手工业、生活服务业];
学科分类号
0805 ; 080502 ; 0822 ;
摘要
Woody (Albizia pedicellaris and Terminalia ivorensis) and non-woody (guinea corn (Sorghum bicolor)) glume and stalk biomass resources from Nigeria were subjected to thermo-analytical and physico-chemical analyses to determine their suitability for thermochemical processing. They were found to have comparably high calorific values (between 16.4 and 20.1 MJ kg(-1)). The woody biomass had very low ash content (0.32%), while the non-woody biomass had relatively high ash content (7.54%). Thermogravimetric analysis (TGA) of the test samples showed significant variation in the decomposition behavior of the individual biomasses. Gas chromatography/mass spectrometry (GC/MS) of fatty acid methyl esters (FAMEs) derivatives indicated the presence of fatty and resin acids in the dichloromethane (CH2Cl2) extracts. Analytical pyrolysis (Py-GC/MS) of the samples revealed that the volatiles liberated consisted mostly of acids, alcohols, ketones, phenols, and sugar derivatives. These biomass types were deemed suitable for biofuel applications.
引用
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页码:5099 / 5113
页数:15
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