Micellar effects on a ligand substitution reaction:: Kinetics of the formation of [Fe(CN)5(μ-pz)Ru(NH3)5]-, from [Fe(CN)5H2O]3- and [Ru(NH3)5pz]2+, in the presence of anionic micelles

被引：18

作者：

Jiménez, R ^{[1
]}

Bueno, E ^{[1
]}

Cano, I ^{[1
]}

Corbacho, E ^{[1
]}

Fernández, ME ^{[1
]}

Gómez, L ^{[1
]}

Graciani, J ^{[1
]}

Hernández, M ^{[1
]}

Matitos, MT ^{[1
]}

Ortíz, J ^{[1
]}

López-Cornejo, P ^{[1
]}

Prado-Gotor, R ^{[1
]}

机构：

[1] Univ Sevilla, Fac Quim, Dept Quim Fis, Seville 41012, Spain

来源：

INTERNATIONAL JOURNAL OF CHEMICAL KINETICS | 2004年 / 36卷 / 12期

关键词：

D O I：

10.1002/kin.20038

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The kinetics of substitution of H2O by Ru(NH3)(5)pz(2+) (pz = pyrazine) in Fe(CN)(5)H2O3- have been studied in micellar aqueous solutions of sodium dodecylsulfate (SDS). Experimental results are discussed by using an approach based on the transition-state theory. This approach is better than others based on the pseudophase model, which can also be used, because it is able to give a clear meaning to the parameters of the model. Trends in the observed reactivity are explained by a change in the degree of association of one of the reactants to the micelles (Ru(NH3)(5)pz(2+) in the present work). This association is governed by an equilibrium constant that depends on the electrostatic potential at the surface of the micelles. (C) 2004 Wiley Periodicals, Inc.

引用

下载

页码：627 / 633

页数：7

共 50 条

[1] Solvent and salt effects on the kinetics of the reaction between [Ru(NH3)5pz]2+ and [Fe(CN)5H2O]3-
Prado-Gotor, R
Ayala, A
Tejeda, AB
Suárez, MB
Mariscal, C
Sánchez, MD
Hierro, G
Lama, A
Aldea, A
Jiménez, R
INTERNATIONAL JOURNAL OF CHEMICAL KINETICS, 2003, 35 (08) : 367 - 373
[2] Asymmetric salt effects on anion/cation reactions:: A comparative study of the [Fe(CN)6]4- +[Co(NH3)5pz]3+ and [Ru(NH3)5pz]2+ + [Co(C2O4)3]3- reactions
Muriel, F
De la Vega, R
Sánchez, F
Jiménez, R
Prado-Gotor, R
Pérez, F
Pérez-Tejeda, P
INTERNATIONAL JOURNAL OF CHEMICAL KINETICS, 2005, 37 (02) : 81 - 89
[3] SOLUTION PROPERTIES OF [(CO)5MO(PZ)] AND [(CO)5MO)2(PZ)] - ORGANOMETALLIC ANALOGS OF [(NH3)5RU(PZ)]2+ AND [(NH3)5RU)2(PZ)]4+ (PZ = PYRAZINE)
ERNHOFFER, R
SHEPHERD, RE
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1978, (20) : 859 - 861
[4] ［Fe(CN)5H2O］3－还原［(NH3)5Co(OOCC5
颜文斌
周朝晖
章慧
徐志固
厦门大学学报(自然科学版), 1995, (03) : 401 - 404
[5] Estimation of electron transfer rate constant from static (optical and thermodynamic) measurements:: A study of Ru(NH3)5pz2++Fe(CN)63-⇆Ru(NH3)5pz3++Fe(CN)64- electron transfer reactions
Sánchez, F
Pérez-Tejeda, P
López-López, M
INORGANIC CHEMISTRY, 1999, 38 (08) : 1780 - 1784
[6] INTERACTION OF HCN WITH [RU(NH3)5H2O]2+
ISIED, SS
TAUBE, H
INORGANIC CHEMISTRY, 1975, 14 (10) : 2561 - 2562
[7] Inner-sphere cluster formation by [Ru(NH3)5H2O]3+ or [Os(NH3)5H2O]3+ in combination with [M(CN)6]4- (M = Fe, Ru, or Os)
Poulopoulou, VG
Taube, H
Nunes, FS
INORGANIC CHEMISTRY, 1999, 38 (12) : 2844 - 2850
[8] Experimental and simulation studies of the electron transfer reaction between [Ru(NH3)5pz]2+ and [Co(C2O4)3]3-
Pérez-Tejeda, P
Franco, FJ
Sánchez, A
Morillo, M
Denk, C
Sánchez, F
PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2001, 3 (07) : 1271 - 1276
[9] Solvent effects on the oxidation (electron transfer) reaction of [Fe(CN)6]4- by [Co(NH3)5pz]3+
Muriel, F
Jiménez, R
López, M
Prado-Gotor, R
Sánchez, F
CHEMICAL PHYSICS, 2004, 298 (1-3) : 317 - 325
[10] Kinetic approach for the study of noncovalent interaction between [Ru(NH3)5pz]2+ and gold nanoparticles
Grueso, E.
Alcantara, D.
Martinez, J.
Mancera, M.
Penades, S.
Sanchez, F.
Pradogotor, R.
JOURNAL OF PHYSICAL CHEMISTRY A, 2007, 111 (39): : 9769 - 9774

← 1 2 3 4 5 →