Transition metal complexes with Girard reagent-based ligands, Part I:: Synthesis and crystal structure of the first cobalt(III) complexes with Schiff base derivative of Girard reagent

被引：26
|
作者：
Vojinovic, LS
Leovac, VM
Novakovic, SB
Bogdanovic, GA
Csanádi, JJ
Cesljevic, VI
机构：
[1] VINCA Inst Nucl Sci, YU-11001 Belgrade, Serbia And Mont, Serbia
[2] Univ Novi Sad, Fac Sci, Dept Chem, YU-21000 Novi Sad, Serbia And Mont, Serbia
来源：
INORGANIC CHEMISTRY COMMUNICATIONS | 2004年 / 7卷 / 12期
关键词：
cobalt(III) complexes; pyridoxilidene Girard-T hydrazone; X-ray crystal structure;
D O I：
10.1016/j.inoche.2004.09.016
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A new ligand, pyridoxilidene Girard-T hydrazone, [H3L]Cl-2 . 2H(2)O, and its octahedral cobalt(III) complexes [Co(HL) (NO2)(3)] . H2O (1) and [Co(HL)(2)](PF6)(3) (2) were synthesized. The X-ray analysis of (1) showed that the complex has a mer-octahedral configuration formed by coordination of the tridentate ONO neutral Schiff-base molecule and three monodentate N-bonded NO2 groups. Hydrogen bonds and intermolecular interactions for this complex are discussed. Complex (2) also has a mer-octahedral configuration. The ligand and complexes were characterized by elemental analysis, conductometric and magnetochemical measurements, IR and UV-Visible, H-1 and C-13 NMR spectra. (C) 2004 Published by Elsevier B.V.
引用
收藏
页码：1264 / 1268
页数：5
相关论文
共 50 条
  • [1] Transition metal complexes with Girard reagent-based ligands. Part III. Synthesis and characterization of salicylaldehyde Girard-T hydrazone complexes. Crystal structure of ligand and two isostructural copper(II) complexes
    Leovac, Vukadin M.
    Bogdanovic, Goran A.
    Cesljevic, Valerija I.
    Jovanovic, Ljiljana S.
    Novakovic, Sladjana B.
    Vojinovic-Jesic, Ljiljana S.
    STRUCTURAL CHEMISTRY, 2007, 18 (01) : 113 - 119
  • [2] Transition metal complexes with Girard reagent-based ligands. Part IV. Synthesis and characterization of pyridoxilidene Girard-T hydrazone complexes. Crystal structure of the copper(II) complex
    Vojinovic-Jesic, Ljiljana S.
    Bogdanovic, Goran A.
    Leovac, Vukadin M.
    Cesljevic, Valerija I.
    Jovanovic, Ljiljana S.
    STRUCTURAL CHEMISTRY, 2008, 19 (05) : 807 - 815
  • [3] Transition metal complexes with Girard reagent-based ligands. Part IV. Synthesis and characterization of pyridoxilidene Girard-T hydrazone complexes. Crystal structure of the copper(II) complex
    Ljiljana S. Vojinović-Ješić
    Goran A. Bogdanović
    Vukadin M. Leovac
    Valerija I. Češljević
    Ljiljana S. Jovanović
    Structural Chemistry, 2008, 19 : 807 - 815
  • [4] Transition metal complexes with Girard reagent-based ligandsPart III. Synthesis and characterization of salicylaldehyde Girard-T hydrazone complexes. Crystal structure of ligand and two isostructural copper(II) complexes
    Vukadin M. Leovac
    Goran A. Bogdanović
    Valerija I. Češljević
    Ljiljana S. Jovanović
    Sladjana B. Novaković
    Ljiljana S. Vojinović-Ješić
    Structural Chemistry, 2007, 18 : 113 - 119
  • [5] Synthesis and structure of iron(III) complexes with a new ligands based on Girard's reagent
    Revenko, M. D.
    Bourosh, P. N.
    Palamarchuk, O. V.
    Lipkowski, J.
    Gdaniec, M.
    Simonov, Yu. A.
    RUSSIAN JOURNAL OF INORGANIC CHEMISTRY, 2009, 54 (10) : 1581 - 1589
  • [6] Synthesis and structure of iron(III) complexes with a new ligands based on Girard’s reagent
    M. D. Revenko
    P. N. Bourosh
    O. V. Palamarchuk
    J. Lipkowski
    M. Gdaniec
    Yu. A. Simonov
    Russian Journal of Inorganic Chemistry, 2009, 54 : 1581 - 1589
  • [7] Synthesis, thermal and spectral studies of first-row transition metal complexes with girard P reagent-based ligand
    El-Ayaan, Usama
    Kenawy, I. M.
    Abu El-Reash, Y. G.
    SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 2007, 68 (02) : 211 - 219
  • [8] Synthesis, thermal and spectral. studies of first-row transition metal complexes with Girard-T reagent-based ligand
    El-Ayaan, Usama
    Kenawy, I. M.
    Abu El-Reash, Y. G.
    JOURNAL OF MOLECULAR STRUCTURE, 2007, 871 (1-3) : 14 - 23
  • [9] Transition metal complexes with Girard reagent-based ligands. Part V. Synthesis, characterization and crystal structure of pentagonal-bipyramidal manganese(II) complex with 2,6-diacetylpyridine bis(Girard-T hydrazone)
    Vojinovic-Jesic, Ljiljana S.
    Cesljevic, Valerija I.
    Bogdanovic, Goran A.
    Leovac, Vukadin M.
    Szecsenyi, Katalin Meszaros
    Divjakovic, Vladimir
    Joksovic, Milan D.
    INORGANIC CHEMISTRY COMMUNICATIONS, 2010, 13 (09) : 1085 - 1088
  • [10] SYNTHESIS, CRYSTAL STRUCTURE AND ANTIMICROBIAL ACTIVITY OF COBALT(III) COMPLEXES WITH SCHIFF BASE LIGANDS
    Feng, Y-X
    Bai, S-Z
    Xue, L-W
    JOURNAL OF STRUCTURAL CHEMISTRY, 2022, 63 (09) : 1509 - 1519
12345