A novel, one-pot and three-component synthesis of α-quinoxalinyl triphenylphosphoranes

被引：14
|
作者：
Adib, Mehdi
Sheibani, Esmaeil
Abbasi, Alireza
Bijanzadeh, Hamid Reza
机构：
[1] Univ Tehran, Sch Chem, Univ Coll Sci, Tehran, Iran
[2] Tarbiat Modares Univ, Dept Chem, Tehran, Iran
来源：
TETRAHEDRON LETTERS | 2007年 / 48卷 / 07期
关键词：
alpha-quinoxalinyl triphenylphosphoranes; diaroylacetylenes; 1,2-benzenediamines; triphenylphosphine; three-component synthesis;
D O I：
10.1016/j.tetlet.2006.12.079
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The reactive 1: 1 zwitterionic intermediate formed by the addition of triphenylphosphine to diaroylacetylenes was trapped with 1,2-benzenediamines to produce triphenylphosphorane intermediates. Intramolecular cyclization and subsequent oxidation of the intermediate afforded functionalized alpha-quinoxalinyl triphenylphosphoranes in good to excellent yields. (c) 2006 Elsevier Ltd. All rights reserved.
引用
收藏
页码：1179 / 1182
页数：4
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