Carbon-coated Ni(OH)2-NiAl LDH hierarchical nanostructures on Ni foam as a high areal capacitance electrode for supercapacitor application

被引:16
|
作者
Li, Xinyue [1 ]
Wan, Gengping [1 ]
Xiao, Jingyue [1 ]
Wu, Lihong [1 ]
Shi, Shaohua [1 ]
Wang, Guizhen [1 ]
机构
[1] Hainan Univ, Minist Educ, Key Lab Adv Mat Trop Isl Resources, Haikou 570228, Hainan, Peoples R China
基金
中国国家自然科学基金;
关键词
Energy storage and conversion; Nanocomposites; Atomic layer deposition; Supercapacitors; LAYERED DOUBLE-HYDROXIDE; GRAPHENE; NANOSHEETS;
D O I
10.1016/j.matlet.2018.06.012
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
In this work, carbon-coated Ni(OH)(2)/NiAl layered double hydroxide hierarchical nanostructures (Ni(OH)(2)/NiAl-LDH@C) in situ grown on Ni foam are synthesized by integrating an atomic layer deposition (ALD) technique with a simple hydrothermal treatment. Such a unique hierarchical structure provides areal capacitance as high as 14.0 F cm(-2) at 5 mA cm(-2) with excellent rate capability (8.09 F cm(-2) at 50 mA cm(-2)), and maintains 87.2% of the initial capacitance even after 2000 cycles. These excellent electrochemical performances demonstrate that the binder-free Ni(OH)(2)/NiAl-LDH@C as battery-like electrode has great competitiveness for supercapacitors in future energy storage applications. (C) 2018 Elsevier B.V. All rights reserved.
引用
收藏
页码:179 / 182
页数:4
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