1,2-ferrocenediylazaphosphinines 2: A new class of nucleophilic catalysts for ring-opening of epoxides

被引：0

作者：

Paek, SH ^{[1
]}

Shim, SC ^{[1
]}

Cho, CS ^{[1
]}

Kim, TJ ^{[1
]}

机构：

[1] Kyungpook Natl Univ, Dept Ind Chem, Taegu 702701, South Korea

来源：

SYNLETT | 2003年 / 06期

关键词：

ferrocenediylazaphosphinines; nucleophilic catalysts; ring-opening; epoxides;

D O I：

暂无

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

1,2-Ferrocenediylazaphosphinines (la-c) have been successfully employed as a new class of nucleophilic catalysts for ring-opening of a range of epoxides, their catalytic efficiency in terms of regioselectivity as well as chemical yield comparing well with the existing catalysts in the literature. In contrast, low enantiomeric excesses have been obtained from the reactions of meso-epoxides catalyzed by (R)-1.

引用

页码：849 / 851

页数：3

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