Chemical reactivities of the cation and anion of M@C82 (M = Y, La, and Ce)

被引：46

作者：

Maeda, Y

Miyashita, J

Hasegawa, T

Wakahara, T

Tsuchiya, T

Feng, L

Lian, YF

Akasaka, T ^{[1
]}

Kobayashi, K

Nagase, S

Kako, M

Yamamoto, K

Kadish, KM

机构：

[1] Tokyo Gakugei Univ, Dept Chem, Koganei, Tokyo 1848501, Japan

[2] Univ Tsukuba, Ctr Tsukuba Adv Res Alliance, Tsukuba, Ibaraki 3058577, Japan

[3] Inst Mol Sci, Dept Theoret Studies, Okazaki, Aichi 4448585, Japan

[4] Univ Electrocommun, Dept Appl Phys & Chem, Tokyo 1828585, Japan

[5] Univ Houston, Dept Chem, Houston, TX 77204 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2005年 / 127卷 / 07期

关键词：

D O I：

10.1021/ja043986b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The chemical reduction and oxidation of M @ C-82 (M = Y, La, and Ce) afford the corresponding anion and cation, respectively, which show unique and interesting chemical reactivities. It is found that the successful reversible gain or loss of electrons by ionization is useful for controlling the stability and reactivity of M @ C-82 toward both nucleophiles and electrophiles.

引用

页码：2143 / 2146

页数：4

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