A novel synthetic route to peralkylated carborane anions, 1-H-CB9Me9- and 1-H-CB11R11- (R = Me, Et)

被引：35
|
作者：
Tsang, CW [1 ]
Xie, ZW [1 ]
机构：
[1] Chinese Univ Hong Kong, Dept Chem, Shatin, Hong Kong, Peoples R China
来源：
CHEMICAL COMMUNICATIONS | 2000年 / 19期
关键词：
D O I：
10.1039/b004737f
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Treatment of carborane anions with excess RBr (R = Me, Et) in a sealed Pyrex tube at 200 degrees C gives peralkylated carborane anions in quantitative yields, which represents the most convenient and the most economic method so far reported in the literature for the preparation of peralkylcarborane anions.
引用
收藏
页码：1839 / 1840
页数：2
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