Multi-walled Carbon Nanotubes Modified ZnO Nanorods: a Photoanode for Photoelectrochemical Cell

被引:25
|
作者
Wei, Yuefan [1 ]
Du, Hejun [1 ]
Kong, Junhua [2 ]
Lu, Xuehong [2 ]
Ke, Lin [3 ]
Sun, Xiao Wei [4 ]
机构
[1] Nanyang Technol Univ, Sch Mech & Aerosp Engn, Singapore 639798, Singapore
[2] Nanyang Technol Univ, Sch Mat Sci & Engn, Singapore 639798, Singapore
[3] Inst Mat Res & Engn, Singapore 117602, Singapore
[4] Nanyang Technol Univ, Sch Elect & Elect Engn, Singapore 639798, Singapore
关键词
photoelectrochemical cell; PEC; ZnO; Multi-walled carbon nanotubes; Photoanode; LOW-TEMPERATURE; SENSITIZED ZNO; WATER; GROWTH; ARRAYS; NANOPARTICLES; DEPOSITION; PERFORMANCE; ELECTRODES; NANOWIRES;
D O I
10.1016/j.electacta.2014.08.026
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
The usage of zinc oxide (ZnO)-based nanostructures in photoelectrochemical (PEC) water splitting has been well investigated yet still in keen exploration for further performance enhancement. Multi-walled carbon nanotubes (MWCNTs)-modified ZnO nanorods were prepared via hydrothermal route followed by simple solution deposition. MWCNTs were self-anchored onto the ZnO nanorods and acted as a hole-attracting phase. The PEC performance of MWCNTs-modified ZnO nanorods, including photocurrent density and photo current conversion efficiency (PCE), was found to be significantly improved compared with unmodified ones. The maximum value of PCE (0.646%), which was 2.1 times higher than that of pristine ZnO nanorods, was achieved with a MWCNTs/ethanol suspension concentration of 0.002 wt%. The performance enhancement is attributed to increasing of light absorption from rougher surface and effective charge carrier transport from the excellent conductivity of the incorporated MWCNTs. (C) 2014 Elsevier Ltd. All rights reserved.
引用
收藏
页码:188 / 195
页数:8
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