On the fluorination of plutonium dioxide by ammonium hydrogen fluoride

被引：23

作者：

Claux, Benoit ^{[1
]}

Benes, Ondrej ^{[1
]}

Capelli, Elisa ^{[1
]}

Soucek, Pavel ^{[1
]}

Meier, Roland ^{[1
]}

机构：

[1] Commiss European Communities, JRC, Inst Transuranium Elements ITU, Postfach 2340, D-76125 Karlsruhe, Germany

来源：

JOURNAL OF FLUORINE CHEMISTRY | 2016年 / 183卷

关键词：

Molten salt reactor; PuF3; synthesis; Fluorination; REACTOR; URANIUM; HEXAFLUORIDE; SYSTEM;

D O I：

10.1016/j.jfluchem.2015.12.009

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A method for synthesis of PuF3 from PuO2 by fluorination using NH4HF2 was investigated. The text comprises the literature study on the published methods for PuF3 syntheses, principles of the applied NH4HF2 fluorination, the developed experimental apparatus, the procedure of the synthesis and analysis of the product. The results showed that the proposed method is well suited for the PuF3 preparation in a sufficient purity and with a good reaction yield. (C) 2016 The Authors. Published by Elsevier B.V.

引用

页码：10 / 13

页数：4

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