Microwave-promoted, one-pot conversion of alkoxymethylated protected alcohols into their corresponding nitriles, bromides, and iodides using [bmim][InCl4] as a green catalyst

被引：18
|
作者：
Mirjafari, Arsalan [1 ]
Mohammadpoor-Baltork, Iraj [1 ]
Moghadam, Majid [1 ]
Tangestaninejad, Shahram [1 ]
Mirkhani, Valiollah [1 ]
Khosropour, Ahmad Reza [1 ]
机构：
[1] Univ Isfahan, Fac Sci, Dept Chem, Catalysis Div, Esfahan 817467344, Iran
来源：
TETRAHEDRON LETTERS | 2010年 / 51卷 / 25期
关键词：
ACIDIC IONIC LIQUIDS; TETRAHYDROPYRANYL ETHERS; TRIMETHYLSILYL; EXTRACTION; REACTIVITY; SOLVENT; REAGENT; V-70;
D O I：
10.1016/j.tetlet.2010.04.056
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The Lewis acid room temperature ionic liquid, [bmim][InCl4], was found to be an efficient and green catalyst for the highly chemoselective and one-pot conversion of MOM- or EOM-ethers into their corresponding nitriles, bromides, and iodides under microwave irradiation. The procedures are simple, rapid, and high yielding. The catalyst exhibited a remarkable reactivity and is reusable. (C) 2010 Elsevier Ltd. All rights reserved.
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收藏
页码：3274 / 3276
页数：3
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