Three-Dimensional Silver-dabco Coordination Polymers with Zeolitic or Three-Connected Topology

被引：13

作者：

Thorp-Greenwood, Flora L. ^{[1
]}

Kulak, Alexander N. ^{[1
]}

Hardie, Michaele J. ^{[1
]}

机构：

[1] Univ Leeds, Sch Chem, Leeds LS2 9JT, W Yorkshire, England

来源：

CRYSTAL GROWTH & DESIGN | 2014年 / 14卷 / 11期

基金：

英国工程与自然科学研究理事会;

关键词：

METAL-ORGANIC FRAMEWORKS; DOT-H-B; CARBABORANE ANIONS; GAS SORPTION; CHEMISTRY; CAPTURE; LIGAND; COPPER; NETWORKS; IODINE;

D O I：

10.1021/cg501231v

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The simple linear linking ligand diazabicyclo[2.2.2]octane (dabco) combines with silver(I) to form three-dimensional (3D) coordination polymers which have either a zeolitic mtn topology structure or a (10,3)-b ths network according to the counteranion used. The tetrahedral anions BF4 or ReO4 promote formation of [Ag(dabco)(2)].X, which has a 3D four-connected mtn framework of fused 5 (12) and 64512 cages, and the material shows modest absorption of iodine. The bulky anion [Co(C2B9H11)(2)]- and an excess of dabco promote formation of complex [Ag-2(dabco)(3)(CH3CN)(2)].(2)[Co(C2B9H11)2(]) with a three-connected (10,3)-b network, while use of 1 equiv of dabco gives a previously reported [Ag(dabco)].[Co(C2B9H11)(2)], which has a one-dimensional coordination chain structure.

引用

页码：5361 / 5365

页数：5

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