CuI@UiO-67-IM: A MOF-Based Bifunctional Composite Triphase-Transfer Catalyst for Sequential One-Pot Azide-Alkyne Cycloaddition in Water

被引：34

作者：

Hu, Yu-Hong ^{[1
]}

Wang, Jian-Cheng ^{[1
]}

Yang, Song ^{[1
]}

Li, Yan-An ^{[1
]}

Dong, Yu-Bin ^{[1
]}

机构：

[1] Shandong Normal Univ, Collaborat Innovat Ctr Functionalized Probes Chem, Coll Chem Chem Engn & Mat Sci, Key Lab Mol & Nano Probes,Minist Educ, Jinan 250014, Shandong, Peoples R China

来源：

INORGANIC CHEMISTRY | 2017年 / 56卷 / 14期

关键词：

METAL-ORGANIC FRAMEWORKS; PHASE-TRANSFER CATALYSIS; QUATERNARY AMMONIUM; HETEROGENEOUS CATALYST; ASYMMETRIC-SYNTHESIS; HIGHLY EFFICIENT; TANDEM REACTION; NANOPARTICLES; ADSORPTION; FUNCTIONALIZATION;

D O I：

10.1021/acs.inorgchem.7b01025

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A CuI-loaded and n-pentadecyl-attached imidazolium salt decorated UiO-67-type metal-organic framework (CuIgUiO-67-IM, 2) based on a new premodified ligand-L (n-pentadecyl-attached imidazolium (IM) decorated dicarboxylic acid) and ZrCl4 is reported. Compound 2 can be a bifunctional composite heterogeneous phase transfer catalyst to promote the azide-alkyne cycloaddition (H2O, air, 80 degrees C) from corresponding halogenated compounds and sodium azide as a sequential one-pot procedure with high yields and excellent regioselectivity.

引用

页码：8341 / 8347

页数：7

共 4 条

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[3] One-Pot Sequential Azide-Alkyne [3+2] Cycloaddition and Atom Transfer Radical Addition (ATRA): Expanding the Scope of In Situ Copper(I) Regeneration in the Presence of Environmentally Benign Reducing Agent
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[J]. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2011, (08) : 1292 - 1301
[4] TiO2@UiO-68-CIL: A Metal-Organic-Framework-Based Bifunctional Composite Catalyst for a One-Pot Sequential Asymmetric Morita-Baylis-Hillman Reaction
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Kan, Xuan
Dong, Yu-Bin
[J]. INORGANIC CHEMISTRY, 2019, 58 (08) : 4722 - 4730

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