Synthesis and structural characterisation of transition metal fluoride sulfates

被引：4
|
作者：
Marshall, Kayleigh L.
Wang, Qianlong
Sullivan, Hannah S. I.
Weller, Mark T. [1 ]
机构：
[1] Univ Bath, Dept Chem, Bath BA2 7AY, Avon, England
来源：
DALTON TRANSACTIONS | 2016年 / 45卷 / 21期
基金：
英国工程与自然科学研究理事会;
关键词：
RECHARGEABLE LITHIUM BATTERIES; SODIUM-ION BATTERIES; FLUOROPHOSPHATE FRAMEWORKS; ANODE; NA; FLUOROSULFATES; CATHODE; ACID; FE;
D O I：
10.1039/c6dt00582a
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Eleven first row transition metal fluoride sulfates synthesised in hydrofluorothermal conditions have been structurally characterised by single crystal X-ray diffraction and exhibit a wide variety of structural motifs. The polyionic structures containing Ti, V, Mn and Fe vary from discrete polyhedral units in Na4TiF4(SO4)(2) and [N2C10H12] TiF4SO4, through one dimensional chains in (K2FeF3SO4, Li3FeF2(SO4)(2)center dot H2O, Li1.87Ti1.13O0.39F1.61(SO4)(2), [N2C10H12]TiF2(SO4)(2), [N2C6H16]Fe(SO4)(2)F and [N2C6H16]V(SO4)(2)F), and to two dimensional layers in ([N2C6H16]2+Mn2F2(SO4)(2), Na2VF3SO4 and Na3CrF2(SO4)(2)).
引用
收藏
页码：8854 / 8861
页数：8
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