Synthesis, crystal structure and electrical conductivity of (bmim)[Pd(dmit)2)]2 (bmim=1-butyl-3-methylimidazolium, dmit=1,3-dithiol-2-thiol-2-thione-4,5-dithiolate)

被引：1
|
作者：
Jia, CY [1 ]
Zhang, DQ [1 ]
Xu, W [1 ]
Shao, XF [1 ]
Zhu, DB [1 ]
机构：
[1] Chinese Acad Sci, Inst Chem, Ctr Mol Sci, Organ Solids Lab, Beijing 100080, Peoples R China
来源：
SYNTHETIC METALS | 2003年 / 137卷 / 1-3期
关键词：
organic conductor; electrocrystalization;
D O I：
10.1016/S0379-6779(02)01085-8
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
The synthesis, structural characterization, and electrical conductivity studies of charge-transfer compound (bmim)[Pd(dmit)(2)](2) was described. This compound was obtained as small needles by electrocrystalization of (bmim)(2)[Pd(dmit)(2)]. Crystallographic parmeters for C20H18N2S20Pd2: monoclinic system; space group: C2/c ; a = 6.3718 (13), b = 14.543 (3), c = 36.339 (7) Angstrom; a = 90, beta = 92.04 (3), gamma = 90; Z = 4, R = 0.0785 (I>2 degrees a (I)). The room temperature conductivity of this salt is 1.2 S . cm(-1), and it shows metallic conducting state in the temperature range of 287-245 K.
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收藏
页码：1345 / 1346
页数：2
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