[{Au[μ-N(SiMe3)2]}4]:: The first base-free gold amide

被引：0
|
作者：
Bunge, SD
Just, O
Rees, WS [1 ]
机构：
[1] Sch Chem & Biochem, Atlanta, GA 30332 USA
[2] Sch Mat Sci & Engn, Atlanta, GA 30332 USA
[3] Inst Mol Design, Atlanta, GA 30332 USA
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2000年 / 39卷 / 17期
关键词：
D O I：
10.1002/1521-3773(20000901)39:17<3082::AID-ANIE3082>3.0.CO;2-2
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Metathetical exchange between LiN(SiMe3)2 and AuCl generated the first tetranuclear (AuN)4 molecular ring, the gold(I) amide [{Au(μ-N-(SiMe3)2]}4]. The cluster is centrosymmetric and comprises an arrangement of four Au atoms (see picture).
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页码：3082 / 3084
页数：3
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