An efficient potassium cyanide-promoted synthesis of 2-arylbenzoxazoles from [4.3.0]boron heterobicycles

被引：12

作者：

Lopez-Ruiz, Heraclio ^{[1
]}

Briseno-Ortega, Horacio ^{[1
]}

Rojas-Lima, Susana ^{[1
]}

Santillan, Rosa ^{[2
]}

Farfan, Norberto ^{[3
]}

机构：

[1] Univ Autonoma Estado Hidalgo, Ctr Invest Quim, Mineral De La Reforma 42184, Mexico

[2] Inst Politecn Nacl, Ctr Invest & Estudios Avanzados, Dept Quim, Mexico City 07000, DF, Mexico

[3] Univ Nacl Autonoma Mexico, Fac Quim, Dept Quim Organ, Mexico City 04510, DF, Mexico

来源：

TETRAHEDRON LETTERS | 2010年 / 51卷 / 19期

关键词：

Schiff bases; Boronates; Potassium cyanide; 2-Arylbenzoxazoles; NMR; PHENOLIC SCHIFFS BASES; DIELS-ALDER REACTION; OXIDATIVE CYCLIZATION; 2-SUBSTITUTED BENZOXAZOLES; STEREOSELECTIVE ADDITION; C=N BOND; BENZOTHIAZOLES; INHIBITORS; ANTAGONIST; LIBRARY;

D O I：

10.1016/j.tetlet.2010.03.027

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The 2-arylbenzoxazoles 3a-f were produced in moderate to excellent yields merely by stirring a potassium cyanide (3 equiv)-containing methanol solution of the borobicyclic compounds 1a-f at room temperature. These compounds were fully characterized spectroscopically [1R, H-1, and C-13 NMR and X-ray analysis (3a)] and by elemental analysis. Crown Copyright (C) 2010 Published by Elsevier Ltd. All rights reserved.

引用

页码：2633 / 2635

页数：3

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