Defect structure of xSc2O3 • (1-x)TiO2 (x=0.4-0.5) solid solutions

被引：4
|
作者：
Lyashenko, L. P. [1 ]
Shcherbakova, L. G. [2 ]
Kulik, E. S. [3 ]
Svetogorov, R. D. [3 ]
Zubavichus, Ya V. [3 ]
机构：
[1] Russian Acad Sci, Inst Problems Chem Phys, Chernogolovka 142432, Moscow Oblast, Russia
[2] Russian Acad Sci, Semenov Inst Chem Phys, Moscow 119991, Russia
[3] Natl Res Ctr, Kurchatov Inst, Moscow 123182, Russia
来源：
INORGANIC MATERIALS | 2015年 / 51卷 / 02期
关键词：
ELECTRICAL-PROPERTIES; STATE;
D O I：
10.1134/S0020168515020120
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
X-ray diffraction characterization with monochromatic synchrotron X-rays has demonstrated that xSc(2)O(3) center dot (1 - x)TiO2 (x = 0.4-0.5) solid solutions consist of a fluorite-like (Fm3m) disordered phase and a nanoscale (a parts per thousand integral 10-50 nm) pyrochlore-like (Fd3m) ordered phase of the same composition, coherent with the disordered phase. We have determined their lattice parameters. The formation of nanodomains with different degrees of order is shown to be caused by the internal strain due to the high density of structural defects in their unit cells. The materials obtained in this study possess enhanced sorption capacity and can be used as catalysts, catalyst supports, gas sensors, etc.
引用
收藏
页码：158 / 162
页数：5
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