Crystal structure and Hirshfeld surface analysis of ((S,S)-2,2′-{(1,2-diphenylethane-1,2-diyl)bis[(azaniumylylidene)methanylylidene]}bis(6-methoxy- phenolato))trinitratosamarium(III)

被引：1
|
作者：
Okumura, Yuta [1 ]
Takiguchi, Yuji [1 ]
Nakane, Daisuke [1 ]
Akitsu, Takashiro [1 ]
机构：
[1] Tokyo Univ Sci, Fac Sci, Dept Chem, Shinjuku Ku, 1-3 Kagurazaka, Tokyo 1628601, Japan
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2021年 / 77卷
关键词：
Schiff base ligand; samarium; chirality; Hirshfeld analysis; crystal structure; SINGLE-MOLECULE MAGNET; COMPLEXES;
D O I：
10.1107/S2056989021004424
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
In the title complex, [Sm(NO3)(3)(C30H28N2O4)], the Sm atom is surrounded by ten O atoms. The (S,S)-2,2'-{[(1,2-diphenylethane-1,2-diyl)bis[(azaniumylylidene)methanylylidene]}bis(6-methoxyphenolate) ligand, obtained from o-vanillin and (1S,2S)-(-)-1,2-diphenylethylenediamine, exhibits a slightly distorted planar arrangement of the four coordinated O atoms. In the crystal, the complex shows intramolecular N-H center dot center dot center dot O hydrogen bonds and weak intermolecular C-H center dot center dot center dot O hydrogen bonds. The Hirshfeld surface analysis indicates that the most important contributions to the packing are from H center dot center dot center dot H (33.5%), O center dot center dot center dot H (34.1%) and C center dot center dot center dot H (21.7%) contacts.
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收藏
页码：579 / +
页数：18
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