Large-Scale Synthesis of SnO2 Nanosheets with High Lithium Storage Capacity

被引：498
|
作者：
Wang, Cen [1 ,2 ]
Zhou, Yun [2 ]
Ge, Mingyuan [1 ,2 ]
Xu, Xiaobin [1 ,2 ]
Zhang, Zaoli [3 ]
Jiang, J. Z. [1 ,2 ]
机构：
[1] Zhejiang Univ, ICNSM, Hangzhou 310027, Peoples R China
[2] Zhejiang Univ, Dept Mat Sci & Engn, Hangzhou 310027, Peoples R China
[3] Austrian Acad Sci, Erich Schmid Inst Mat Sci, A-8700 Leoben, Austria
来源：
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2010年 / 132卷 / 01期
基金：
中国国家自然科学基金;
关键词：
ONE-POT SYNTHESIS; ION BATTERIES; MESOPOROUS SNO2; POROUS SNO2; NANOTUBES; TIN; NANOSTRUCTURES; MICROSPHERES; ELECTRODES; COMPOSITE;
D O I：
10.1021/ja909321d
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
In this communication, we successfully synthesized a new SnO2 nanoarchitecture: extremely thin sheets, with minimum thicknesses of 1.5-3.0 nm. The products were prepared through a facile hydrothermal treatment using tin dichloride as the precursor. Planar or scrolled SnO2 sheets were carefully examined by transmission electron microscopy. The assemblies of these sheets have a high BET surface area of 180.3 m(2)/g and extraordinarily large pore volume of 1.028 cm(3)/g. They also exhibit a high lithium storage capacity and excellent cyclability due to its nanometer-sized frame and breathable characteristic.
引用
收藏
页码：46 / +
页数：4
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