A visually detectable pH responsive zirconium metal-organic framework

被引：53
|
作者：
Moon, Su-Young [1 ]
Howarth, Ashlee J. [1 ]
Wang, Timothy [1 ]
Vermeulen, Nicolaas A. [1 ]
Hupp, Joseph T. [1 ]
Farha, Omar K. [1 ,2 ]
机构：
[1] Northwestern Univ, Dept Chem, 2145 Sheridan Rd, Evanston, IL 60208 USA
[2] Univ Jeddah, Fac Sci King Abdulaziz, Dept Chem, Jeddah, Saudi Arabia
来源：
CHEMICAL COMMUNICATIONS | 2016年 / 52卷 / 16期
关键词：
ASSISTED LIGAND INCORPORATION; CHEMICAL-WARFARE AGENTS; FUNCTIONALIZATION; MACROPHAGES; HYDROLYSIS; ADSORPTION; DEPOSITION; SIMULANTS; NU-1000; STORAGE;
D O I：
10.1039/c5cc10384c
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A halochromic Zr-6-based metal-organic framework is synthesized using solvent-assisted linker incorporation (SALI) with NU-1000 as a platform and carboxylnaphthofluorescein as a pH sensitive ligand. The functionalizedMOF can catalytically detoxify nerve agent simulants in addition to visually detecting the acidic byproduct produced during detoxification.
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页码：3438 / 3441
页数：4
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