Co-production of hydrogen and electricity from autothermal reforming of natural gas by means of Pd-Ag membranes

被引:3
|
作者
Manzolini, Giampaolo [1 ]
Vigano, Federico [1 ]
机构
[1] Politecn Milan, Dept Energy, IT-20133 Milan, Italy
来源
关键词
Hydrogen production; Natural gas reforming; CCS; Selective membranes; HSMR; WGS; Autothermal reforming;
D O I
10.1016/j.egypro.2009.01.044
中图分类号
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号
0807 ; 0820 ;
摘要
In this paper, the use of two Water Gas Shift (WGS) Hydrogen Separator Membrane Reactors (HSMRs) is proposed downstream of a natural gas Autothermal Reformer (ATR), for hydrogen and electricity co-production with low carbon dioxide emissions. Starting from an advanced ATR plant based on state-of-the-art technologies with carbon capture, a novel configuration is proposed. Application of HSMRs allows a significant layout simplification and the reduction of the number of components. Hydrogen separation by means of membrane reactors allows carbon capture higher than 99% compared to 87% of the reference case. Simulation results show that the membrane based power plant achieves higher equivalent fuel conversion efficiency even with a significant amount of electricity produced. Moreover, the innovative solution allows to produce electricity and hydrogen at different ratio without affecting the overall performances. (C) 2008 Elsevier Ltd. All rights reserved
引用
收藏
页码:319 / 326
页数:8
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